AM-4VP阴离子交换树脂在硝酸溶液中回收锕系元素过程中的耐辐射性能

IF 1 Q4 CHEMISTRY, INORGANIC & NUCLEAR
E. V. Lyzlova, A. V. Glukhova, L. V. Chernavskaya, A. V. Shcherbakov, A. V. Konnikov, M. S. Lysenko
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引用次数: 0

摘要

对斯莫利公司生产的AM-4VP大孔阴离子交换树脂的耐辐射性能进行了评价。研究了辐射吸收剂量对AM-4VP树脂物理性能和吸钍性能的影响。在未辐照和辐照后的AM-4VP阴离子交换树脂样品上进行了工艺溶液中钚的动态回收实验。并与之前使用的VP-1Ap阴离子交换树脂的耐辐射性能进行了比较。在吸收的γ辐射不超过2 MGy时,AM-4VP阴离子交换树脂的物理特性和对钚的吸附性能仍然可以接受,实际上并不逊于VP-1Ap树脂。在吸收的γ辐射剂量为5 MGy时,AM-4VP和VP-1Ap树脂发生了大量的辐射化学转变,导致其吸收能力几乎完全丧失。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Radiation Resistance of AM-4VP Anion-Exchange Resin in the Course of Recovering Actinides from Nitric Acid Solutions

Radiation Resistance of AM-4VP Anion-Exchange Resin in the Course of Recovering Actinides from Nitric Acid Solutions

The radiation resistance of the AM-4VP macroporous anion-exchange resin producted by Smoly Corporate Group was evaluated. The influence of the absorbed radiation dose on the physical properties of the AM-4VP resin and on its performance in thorium sorption was examined. Experiments were performed on the plutonium recovery from process solutions in the dynamic mode on nonirradiated and irradiated samples of the AM-4VP anion-exchange resin. The radiation resistance of the resin was compared to that of VP-1Ap anion-exchange resin used in the process previously. At the absorbed γ-radiation does not exceeding 2 MGy, the physical characteristics of the AM-4VP anion-exchange resin and its performance in the plutonium sorption remain acceptable and practically are not inferior to those of the VP-1Ap resin. At the absorbed γ-radiation dose of 5 MGy, the AM-4VP and VP-1Ap resins undergo substantial radiation-chemical transformations leading to the virtually complete loss of their sorption ability.

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来源期刊
Radiochemistry
Radiochemistry CHEMISTRY, INORGANIC & NUCLEAR-
CiteScore
1.30
自引率
33.30%
发文量
51
期刊介绍: Radiochemistry  is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
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