{"title":"新型硼酸基紫外发射材料:LiSrBO3:Pb2+","authors":"İlhan Pekgözlü","doi":"10.1007/s10812-025-01919-9","DOIUrl":null,"url":null,"abstract":"<p>LiSr<sub>1–<i>x</i></sub>Pb<sub><i>x</i></sub>BO<sub>3</sub> (<i>x</i> = 0, 0.0025, and 0.005) materials were synthesized at 750°C for 6 h in air. Powder X-ray diffraction and FTIR were used to determine the phase and bond structure of the synthesized LiSrBO<sub>3</sub>. Spectrofl uorometry was used to investigate the photoluminescence properties of the prepared phosphors at room temperature. LiSrBO<sub>3</sub>:Pb<sup>2+</sup> was found to have emission and excitation bands at 362 and 275 nm, respectively. Finally, the prepared material LiSrBO<sub>3</sub>:Pb<sup>2+</sup> was found to have a Stokes shift of 8739 cm<sup>–1</sup>, using the excitation band at 275 nm and the emission band at 362 nm. As a result of this work, a new UVA radiation-emitting substance has been introduced to the literature.</p>","PeriodicalId":609,"journal":{"name":"Journal of Applied Spectroscopy","volume":"92 2","pages":"352 - 355"},"PeriodicalIF":1.0000,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Novel Borate-Based UV-Emitting Material: LiSrBO3:Pb2+\",\"authors\":\"İlhan Pekgözlü\",\"doi\":\"10.1007/s10812-025-01919-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>LiSr<sub>1–<i>x</i></sub>Pb<sub><i>x</i></sub>BO<sub>3</sub> (<i>x</i> = 0, 0.0025, and 0.005) materials were synthesized at 750°C for 6 h in air. Powder X-ray diffraction and FTIR were used to determine the phase and bond structure of the synthesized LiSrBO<sub>3</sub>. Spectrofl uorometry was used to investigate the photoluminescence properties of the prepared phosphors at room temperature. LiSrBO<sub>3</sub>:Pb<sup>2+</sup> was found to have emission and excitation bands at 362 and 275 nm, respectively. Finally, the prepared material LiSrBO<sub>3</sub>:Pb<sup>2+</sup> was found to have a Stokes shift of 8739 cm<sup>–1</sup>, using the excitation band at 275 nm and the emission band at 362 nm. As a result of this work, a new UVA radiation-emitting substance has been introduced to the literature.</p>\",\"PeriodicalId\":609,\"journal\":{\"name\":\"Journal of Applied Spectroscopy\",\"volume\":\"92 2\",\"pages\":\"352 - 355\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2025-05-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Spectroscopy\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10812-025-01919-9\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"SPECTROSCOPY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10812-025-01919-9","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
LiSr1–xPbxBO3 (x = 0, 0.0025, and 0.005) materials were synthesized at 750°C for 6 h in air. Powder X-ray diffraction and FTIR were used to determine the phase and bond structure of the synthesized LiSrBO3. Spectrofl uorometry was used to investigate the photoluminescence properties of the prepared phosphors at room temperature. LiSrBO3:Pb2+ was found to have emission and excitation bands at 362 and 275 nm, respectively. Finally, the prepared material LiSrBO3:Pb2+ was found to have a Stokes shift of 8739 cm–1, using the excitation band at 275 nm and the emission band at 362 nm. As a result of this work, a new UVA radiation-emitting substance has been introduced to the literature.
期刊介绍:
Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.