RILEM TC 301-ASR报告:孔隙溶液组成与ASR膨胀的关系

IF 3.9 3区 工程技术 Q2 CONSTRUCTION & BUILDING TECHNOLOGY
Barbara Lothenbach, Miriam E. Krüger, Maxime Ranger, Ana Bergmann, Petter Hemstad, Jan Lindgård, Doug Hooton, Josée Duchesne, Andreas Leemann, Klaartje De Weerdt
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引用次数: 0

摘要

决定混凝土中碱-硅反应(ASR)风险的一个重要参数是碱离子的可用性,因为它们与孔溶液中的OH -浓度密切相关。从文献资料中比较混凝土或砂浆与水泥的膨胀和孔隙溶液组成,膨胀与水泥的总碱含量没有明显的关系。然而,观察到的膨胀强烈依赖于孔溶液中的碱和氢氧化物浓度。当孔隙溶液中的氢氧化物浓度大于250 mmol/L或(Na + K)浓度大于300-400 mmol/L时,在接近环境温度(20-40°C)下暴露的实验室样品中研究的高活性聚集体会发生显著的ASR膨胀。反应性较差的聚集体具有较高的“碱阈值”。在60°C和80°C时,由于温度影响了许多可以加速或减缓ASR的因素,孔隙溶解和膨胀之间的相关性趋于瓦解。高铝浓度的孔隙溶液和低欠饱和度的二氧化硅被认为可以减缓ASR的形成。孔隙溶液中的Al浓度和SiO2的欠饱和都不是ASR膨胀的选择性标准。pH值的测量高度依赖于温度,难以测量,并且使用各种技术确定,这些技术通常解释不清。因此,孔隙溶液的pH值本身并不是评价ASR扩张风险的好方法,尽管本研究表明pH值与膏体孔隙溶液中(Na + K)浓度的和有很好的相关性。建议使用(Na + K)作为最可靠和相对容易获得的参数,以表示高达40°C的混凝土或砂浆中ASR的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Report of RILEM TC 301-ASR: relation between pore solution composition and ASR expansion

An important parameter determining the risk of alkali-silica reaction (ASR) in concrete is the availability of alkali ions as they are closely related to the OH concentration in the pore solution. Comparison of concrete or mortar expansion with cement and pore solution composition from literature data showed no obvious relationship of the expansion with the total alkali content of the cement. However, the observed expansion was strongly dependent on the alkali and hydroxide concentrations in the pore solution. At a hydroxide concentration greater than 250 mmol/L in the pore solution or at (Na + K) concentrations greater than 300–400 mmol/L, significant ASR expansion took place for the highly reactive aggregates studied in the laboratory samples exposed at near ambient temperatures (20–40 °C). Less reactive aggregates will have a higher “alkali threshold”. At 60 and 80 °C correlations between pore solution and expansion tend to fall apart as temperature influences many factors that can accelerate or slow down ASR. High Al concentration in the pore solution as well as a low undersaturation with respect to silica have been suggested to slow down ASR formation. Neither the Al concentration in the pore solution nor undersaturation with respect to SiO2 was found to be selective criteria for ASR expansion. The pH measurements are highly dependent on temperature, difficult to measure, and determined using a variety of techniques that are frequently poorly explained. The pore solution’s pH by itself is therefore not a good way to evaluate the risk of ASR expansion, although this study showed that there is a good correlation between pH and the sum of (Na + K) concentration in the paste pore solution. It is recommended that (Na + K) is used as the most reliable and relatively easily accessible parameter to indicate the potential for ASR in concretes or mortars up to 40 °C.

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来源期刊
Materials and Structures
Materials and Structures 工程技术-材料科学:综合
CiteScore
6.40
自引率
7.90%
发文量
222
审稿时长
5.9 months
期刊介绍: Materials and Structures, the flagship publication of the International Union of Laboratories and Experts in Construction Materials, Systems and Structures (RILEM), provides a unique international and interdisciplinary forum for new research findings on the performance of construction materials. A leader in cutting-edge research, the journal is dedicated to the publication of high quality papers examining the fundamental properties of building materials, their characterization and processing techniques, modeling, standardization of test methods, and the application of research results in building and civil engineering. Materials and Structures also publishes comprehensive reports prepared by the RILEM’s technical committees.
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