胺改性低成本支撑型钢渣燃烧后CO2捕集研究

IF 3.2 4区 工程技术 Q2 CHEMISTRY, MULTIDISCIPLINARY
Wenhao Liu, Qingcai Chen, Tengfei Xu
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引用次数: 0

摘要

为了降低固胺技术的CO2捕集成本,利用固体废弃物源制备支撑材料受到了越来越多的关注。我们采用碱性氧炉钢渣和高炉矿渣为原料。为获得多孔支撑材料,分别对其进行酸蚀和酸碱联合处理。然后用TEPA对其进行改性,最终成功制备了两种钢渣基固体胺材料(BOFS-xTEPA和BFSX-xTEPA)。采用XRF、BET、SEM等技术对材料进行了表征。利用自制的静态CO2吸附容量测试仪测试了复合材料在15% CO2和85%空气(湿)条件下的CO2吸附能力。通过控制材料合成过程中的参数,探索最佳的CO2吸附量。从机理上为两种多孔支撑材料的成孔提供了合理的解释。最后,从多个角度分析了两种钢渣基固体胺制备路线的特点。并与其他固体废物来源的固体胺进行了比较,说明了该项目的优势。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A Low-Cost Support Derived Steel Slag with Amine Modification for Post-combustion CO2 Capture

To reduce the CO2 capture cost of solid amine technology, more attention has been paid to the preparation of support materials from solid waste sources. We use basic oxygen furnace steel slag and blast furnace slag as raw materials. To obtain porous support materials, they are treated by acid etching and combined acid-base treatment, respectively. Then modified them using TEPA, finally successfully prepared two types of steel slag-based solid amine materials (BOFS-xTEPA and BFSX-xTEPA). The technologies of XRF, BET and SEM were used to characterize the materials. A homemade static CO2 adsorption capacity tester was utilized to test the CO2 adsorption capacity of the composites at 15% CO2 and 85% air (wet). The optimal CO2 adsorption capacity was explored by controlling the parameters in the material synthesis process. In terms of mechanism, a rational explanation for the pore formation of the two porous support materials was provided. Finally, the characteristics of the two steel slag-based solid amine preparation routes were analyzed from various perspectives. In comparison with solid amines derived from other solid waste sources, the advantages of this project were elucidated.

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来源期刊
Korean Journal of Chemical Engineering
Korean Journal of Chemical Engineering 工程技术-工程:化工
CiteScore
4.60
自引率
11.10%
发文量
310
审稿时长
4.7 months
期刊介绍: The Korean Journal of Chemical Engineering provides a global forum for the dissemination of research in chemical engineering. The Journal publishes significant research results obtained in the Asia-Pacific region, and simultaneously introduces recent technical progress made in other areas of the world to this region. Submitted research papers must be of potential industrial significance and specifically concerned with chemical engineering. The editors will give preference to papers having a clearly stated practical scope and applicability in the areas of chemical engineering, and to those where new theoretical concepts are supported by new experimental details. The Journal also regularly publishes featured reviews on emerging and industrially important subjects of chemical engineering as well as selected papers presented at international conferences on the subjects.
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