{"title":"胺改性低成本支撑型钢渣燃烧后CO2捕集研究","authors":"Wenhao Liu, Qingcai Chen, Tengfei Xu","doi":"10.1007/s11814-025-00482-5","DOIUrl":null,"url":null,"abstract":"<div><p>To reduce the CO<sub>2</sub> capture cost of solid amine technology, more attention has been paid to the preparation of support materials from solid waste sources. We use basic oxygen furnace steel slag and blast furnace slag as raw materials. To obtain porous support materials, they are treated by acid etching and combined acid-base treatment, respectively. Then modified them using TEPA, finally successfully prepared two types of steel slag-based solid amine materials (BOFS-xTEPA and BFSX-xTEPA). The technologies of XRF, BET and SEM were used to characterize the materials. A homemade static CO<sub>2</sub> adsorption capacity tester was utilized to test the CO<sub>2</sub> adsorption capacity of the composites at 15% CO<sub>2</sub> and 85% air (wet). The optimal CO<sub>2</sub> adsorption capacity was explored by controlling the parameters in the material synthesis process. In terms of mechanism, a rational explanation for the pore formation of the two porous support materials was provided. Finally, the characteristics of the two steel slag-based solid amine preparation routes were analyzed from various perspectives. In comparison with solid amines derived from other solid waste sources, the advantages of this project were elucidated.</p></div>","PeriodicalId":684,"journal":{"name":"Korean Journal of Chemical Engineering","volume":"42 8","pages":"1587 - 1598"},"PeriodicalIF":3.2000,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Low-Cost Support Derived Steel Slag with Amine Modification for Post-combustion CO2 Capture\",\"authors\":\"Wenhao Liu, Qingcai Chen, Tengfei Xu\",\"doi\":\"10.1007/s11814-025-00482-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>To reduce the CO<sub>2</sub> capture cost of solid amine technology, more attention has been paid to the preparation of support materials from solid waste sources. We use basic oxygen furnace steel slag and blast furnace slag as raw materials. To obtain porous support materials, they are treated by acid etching and combined acid-base treatment, respectively. Then modified them using TEPA, finally successfully prepared two types of steel slag-based solid amine materials (BOFS-xTEPA and BFSX-xTEPA). The technologies of XRF, BET and SEM were used to characterize the materials. A homemade static CO<sub>2</sub> adsorption capacity tester was utilized to test the CO<sub>2</sub> adsorption capacity of the composites at 15% CO<sub>2</sub> and 85% air (wet). The optimal CO<sub>2</sub> adsorption capacity was explored by controlling the parameters in the material synthesis process. In terms of mechanism, a rational explanation for the pore formation of the two porous support materials was provided. Finally, the characteristics of the two steel slag-based solid amine preparation routes were analyzed from various perspectives. In comparison with solid amines derived from other solid waste sources, the advantages of this project were elucidated.</p></div>\",\"PeriodicalId\":684,\"journal\":{\"name\":\"Korean Journal of Chemical Engineering\",\"volume\":\"42 8\",\"pages\":\"1587 - 1598\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2025-05-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Korean Journal of Chemical Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11814-025-00482-5\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Korean Journal of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11814-025-00482-5","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A Low-Cost Support Derived Steel Slag with Amine Modification for Post-combustion CO2 Capture
To reduce the CO2 capture cost of solid amine technology, more attention has been paid to the preparation of support materials from solid waste sources. We use basic oxygen furnace steel slag and blast furnace slag as raw materials. To obtain porous support materials, they are treated by acid etching and combined acid-base treatment, respectively. Then modified them using TEPA, finally successfully prepared two types of steel slag-based solid amine materials (BOFS-xTEPA and BFSX-xTEPA). The technologies of XRF, BET and SEM were used to characterize the materials. A homemade static CO2 adsorption capacity tester was utilized to test the CO2 adsorption capacity of the composites at 15% CO2 and 85% air (wet). The optimal CO2 adsorption capacity was explored by controlling the parameters in the material synthesis process. In terms of mechanism, a rational explanation for the pore formation of the two porous support materials was provided. Finally, the characteristics of the two steel slag-based solid amine preparation routes were analyzed from various perspectives. In comparison with solid amines derived from other solid waste sources, the advantages of this project were elucidated.
期刊介绍:
The Korean Journal of Chemical Engineering provides a global forum for the dissemination of research in chemical engineering. The Journal publishes significant research results obtained in the Asia-Pacific region, and simultaneously introduces recent technical progress made in other areas of the world to this region. Submitted research papers must be of potential industrial significance and specifically concerned with chemical engineering. The editors will give preference to papers having a clearly stated practical scope and applicability in the areas of chemical engineering, and to those where new theoretical concepts are supported by new experimental details. The Journal also regularly publishes featured reviews on emerging and industrially important subjects of chemical engineering as well as selected papers presented at international conferences on the subjects.