{"title":"揭示天然橡胶非橡胶组分对其耐辐射性能的影响","authors":"En-Tao Luo, Liang Jing, Ling-Min Kong, Yu Peng, Hao Luo, Li-Juan Zhao, Zheng-Tian Xie, Jin-Rong Wu","doi":"10.1007/s10118-025-3330-x","DOIUrl":null,"url":null,"abstract":"<div><p>Natural rubber (NR) is a crucial elastic material used for damping and sealing applications in the nuclear industry, but its mechanical stability under radiation remains inadequate. Current efforts to improve radiation resistance rely on the addition of antiradiation agents, however, the effects of the components and microstructures of NR itself on radiation resistance remain unclear. In this study, we compared the composition and structure differences of four typical commercially used NR materials and investigated their effects on gamma radiation resistance. Furthermore, we examined the impact of non-rubber components (NRC) in NR on radiation resistance using deproteinized and dephosphorylated NR model samples. Our results revealed that NRC, such as proteins and phospholipids can enhance the strength of natural rubber before radiation exposure. However, after the removal of NRC, the samples exhibited improved mechanical stability under irradiation. Additionally, the ash content in NR could also influence the radiation resistance, as metal ions may react with the active centers produced by radiation, thereby enhancing the radiation resistance of the rubber. This work identifies the effect of non-rubber components in NR on radiation resistance and may serve as a reference for screening and developing radiation-resistant NR materials.</p></div>","PeriodicalId":517,"journal":{"name":"Chinese Journal of Polymer Science","volume":"43 7","pages":"1190 - 1199"},"PeriodicalIF":4.0000,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Revealing the Effect of Non-rubber Components of Natural Rubber on Its Radiation Resistance Performance\",\"authors\":\"En-Tao Luo, Liang Jing, Ling-Min Kong, Yu Peng, Hao Luo, Li-Juan Zhao, Zheng-Tian Xie, Jin-Rong Wu\",\"doi\":\"10.1007/s10118-025-3330-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Natural rubber (NR) is a crucial elastic material used for damping and sealing applications in the nuclear industry, but its mechanical stability under radiation remains inadequate. Current efforts to improve radiation resistance rely on the addition of antiradiation agents, however, the effects of the components and microstructures of NR itself on radiation resistance remain unclear. In this study, we compared the composition and structure differences of four typical commercially used NR materials and investigated their effects on gamma radiation resistance. Furthermore, we examined the impact of non-rubber components (NRC) in NR on radiation resistance using deproteinized and dephosphorylated NR model samples. Our results revealed that NRC, such as proteins and phospholipids can enhance the strength of natural rubber before radiation exposure. However, after the removal of NRC, the samples exhibited improved mechanical stability under irradiation. Additionally, the ash content in NR could also influence the radiation resistance, as metal ions may react with the active centers produced by radiation, thereby enhancing the radiation resistance of the rubber. This work identifies the effect of non-rubber components in NR on radiation resistance and may serve as a reference for screening and developing radiation-resistant NR materials.</p></div>\",\"PeriodicalId\":517,\"journal\":{\"name\":\"Chinese Journal of Polymer Science\",\"volume\":\"43 7\",\"pages\":\"1190 - 1199\"},\"PeriodicalIF\":4.0000,\"publicationDate\":\"2025-04-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chinese Journal of Polymer Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10118-025-3330-x\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chinese Journal of Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10118-025-3330-x","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Revealing the Effect of Non-rubber Components of Natural Rubber on Its Radiation Resistance Performance
Natural rubber (NR) is a crucial elastic material used for damping and sealing applications in the nuclear industry, but its mechanical stability under radiation remains inadequate. Current efforts to improve radiation resistance rely on the addition of antiradiation agents, however, the effects of the components and microstructures of NR itself on radiation resistance remain unclear. In this study, we compared the composition and structure differences of four typical commercially used NR materials and investigated their effects on gamma radiation resistance. Furthermore, we examined the impact of non-rubber components (NRC) in NR on radiation resistance using deproteinized and dephosphorylated NR model samples. Our results revealed that NRC, such as proteins and phospholipids can enhance the strength of natural rubber before radiation exposure. However, after the removal of NRC, the samples exhibited improved mechanical stability under irradiation. Additionally, the ash content in NR could also influence the radiation resistance, as metal ions may react with the active centers produced by radiation, thereby enhancing the radiation resistance of the rubber. This work identifies the effect of non-rubber components in NR on radiation resistance and may serve as a reference for screening and developing radiation-resistant NR materials.
期刊介绍:
Chinese Journal of Polymer Science (CJPS) is a monthly journal published in English and sponsored by the Chinese Chemical Society and the Institute of Chemistry, Chinese Academy of Sciences. CJPS is edited by a distinguished Editorial Board headed by Professor Qi-Feng Zhou and supported by an International Advisory Board in which many famous active polymer scientists all over the world are included. The journal was first published in 1983 under the title Polymer Communications and has the current name since 1985.
CJPS is a peer-reviewed journal dedicated to the timely publication of original research ideas and results in the field of polymer science. The issues may carry regular papers, rapid communications and notes as well as feature articles. As a leading polymer journal in China published in English, CJPS reflects the new achievements obtained in various laboratories of China, CJPS also includes papers submitted by scientists of different countries and regions outside of China, reflecting the international nature of the journal.