{"title":"三氟乙酸酯前驱体热分解制备的Tysonite结构纳米氟化物（Ce1-xPrx）0.95Sr0.05F2.95的陶瓷合成及离子电导率","authors":"N. I. Sorokin, A. V. Koshelev, D. N. Karimov","doi":"10.1134/S2635167625600099","DOIUrl":null,"url":null,"abstract":"<p>Nanosized powders (Ce<sub>1–<i>x</i></sub>Pr<sub><i>x</i></sub>)<sub>0.95</sub>Sr<sub>0.05</sub>F<sub>2.95</sub> (<i>x</i> = 0, 0.5, 1) with a tysonite structure (sp. gr. <span>\\(P\\bar {3}c1\\)</span>) are synthesized by the thermal decomposition of trifluoroacetate precursors in an inert environment. The ceramics are cold pressed, and their X-ray and conductometric properties are studied. It is found that the mixed composition nanoceramics (Ce<sub>0.5</sub>Pr<sub>0.5</sub>)<sub>0.95</sub>Sr<sub>0.05</sub>F<sub>2.95</sub> (<i>x</i> = 0.5) demonstrate a higher electrolytic characteristics compared to the compositions with <i>x</i> = 0 and 1. The value of its ionic conductivity is σ<sub><i>dc</i></sub> = 6.5 × 10<sup>‒3</sup> S/cm at 500 K. The cation composition of the studied solid electrolyte (Ce<sub>0.5</sub>Pr<sub>0.5</sub>)<sub>0.95</sub>Sr<sub>0.05</sub>F<sub>2.95</sub> is promising for further optimization of the ceramic synthesis process and application in various electrochemical devices.</p>","PeriodicalId":716,"journal":{"name":"Nanotechnologies in Russia","volume":"20 2","pages":"174 - 180"},"PeriodicalIF":0.8000,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ceramic Synthesis and Ionic Conductivity of Nanofluorides (Ce1–xPrx)0.95Sr0.05F2.95 with a Tysonite Structure Prepared by Thermal Decomposition of Trifluoroacetate Precursors\",\"authors\":\"N. I. Sorokin, A. V. Koshelev, D. N. Karimov\",\"doi\":\"10.1134/S2635167625600099\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Nanosized powders (Ce<sub>1–<i>x</i></sub>Pr<sub><i>x</i></sub>)<sub>0.95</sub>Sr<sub>0.05</sub>F<sub>2.95</sub> (<i>x</i> = 0, 0.5, 1) with a tysonite structure (sp. gr. <span>\\\\(P\\\\bar {3}c1\\\\)</span>) are synthesized by the thermal decomposition of trifluoroacetate precursors in an inert environment. The ceramics are cold pressed, and their X-ray and conductometric properties are studied. It is found that the mixed composition nanoceramics (Ce<sub>0.5</sub>Pr<sub>0.5</sub>)<sub>0.95</sub>Sr<sub>0.05</sub>F<sub>2.95</sub> (<i>x</i> = 0.5) demonstrate a higher electrolytic characteristics compared to the compositions with <i>x</i> = 0 and 1. The value of its ionic conductivity is σ<sub><i>dc</i></sub> = 6.5 × 10<sup>‒3</sup> S/cm at 500 K. The cation composition of the studied solid electrolyte (Ce<sub>0.5</sub>Pr<sub>0.5</sub>)<sub>0.95</sub>Sr<sub>0.05</sub>F<sub>2.95</sub> is promising for further optimization of the ceramic synthesis process and application in various electrochemical devices.</p>\",\"PeriodicalId\":716,\"journal\":{\"name\":\"Nanotechnologies in Russia\",\"volume\":\"20 2\",\"pages\":\"174 - 180\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2025-07-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanotechnologies in Russia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S2635167625600099\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanotechnologies in Russia","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S2635167625600099","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Engineering","Score":null,"Total":0}
Ceramic Synthesis and Ionic Conductivity of Nanofluorides (Ce1–xPrx)0.95Sr0.05F2.95 with a Tysonite Structure Prepared by Thermal Decomposition of Trifluoroacetate Precursors
Nanosized powders (Ce1–xPrx)0.95Sr0.05F2.95 (x = 0, 0.5, 1) with a tysonite structure (sp. gr. \(P\bar {3}c1\)) are synthesized by the thermal decomposition of trifluoroacetate precursors in an inert environment. The ceramics are cold pressed, and their X-ray and conductometric properties are studied. It is found that the mixed composition nanoceramics (Ce0.5Pr0.5)0.95Sr0.05F2.95 (x = 0.5) demonstrate a higher electrolytic characteristics compared to the compositions with x = 0 and 1. The value of its ionic conductivity is σdc = 6.5 × 10‒3 S/cm at 500 K. The cation composition of the studied solid electrolyte (Ce0.5Pr0.5)0.95Sr0.05F2.95 is promising for further optimization of the ceramic synthesis process and application in various electrochemical devices.
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Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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