{"title":"用CdSeTe量子点修饰矿物油,提高了高压应用中的稳定性和介电性能","authors":"Yunus Biçen, Erdem Elibol, Tuna Demirci","doi":"10.1007/s11051-025-06389-w","DOIUrl":null,"url":null,"abstract":"<div><p>This study explored the application of CdSeTe quantum dots (QDs) in mineral oils for high-voltage applications through a comprehensive approach. CdSeTe QDs were synthesized using an organometallic method and added to mineral oil at concentrations of 1 mg/L (C1), 5 mg/L (C2), and 10 mg/L (C3). The samples’ stability condition was monitored for a long period, and physicochemical tests were performed. Experimental results show that QD-modified oils have enhanced electrical properties compared to the base oil. The breakdown voltage was in the range of 17 to 23 kV for the base oil, while the breakdown voltage was in the range of 20 to 39 kV for the QD-modified (C2) insulating fluid sample. Throughout the 25-day monitoring period, the QDs were found to be properly dispersed in oil and free of aggregation in all samples. Values such as density and viscosity remained fairly constant due to the relatively low concentration ratio. However, an increase in total acid number was observed with increasing concentration. These results imply that QD-enhanced insulation oils may have applications in high-voltage applications in the future. The main innovation of this study lies in demonstrating that CdSeTe QDs can significantly enhance the dielectric strength of mineral oils while maintaining their essential physicochemical properties, offering a novel approach for improving insulation performance in high-voltage applications.</p></div>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":"27 7","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2025-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mineral oils modified with CdSeTe QDs for improved stability and dielectric performance in high-voltage applications\",\"authors\":\"Yunus Biçen, Erdem Elibol, Tuna Demirci\",\"doi\":\"10.1007/s11051-025-06389-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This study explored the application of CdSeTe quantum dots (QDs) in mineral oils for high-voltage applications through a comprehensive approach. CdSeTe QDs were synthesized using an organometallic method and added to mineral oil at concentrations of 1 mg/L (C1), 5 mg/L (C2), and 10 mg/L (C3). The samples’ stability condition was monitored for a long period, and physicochemical tests were performed. Experimental results show that QD-modified oils have enhanced electrical properties compared to the base oil. The breakdown voltage was in the range of 17 to 23 kV for the base oil, while the breakdown voltage was in the range of 20 to 39 kV for the QD-modified (C2) insulating fluid sample. Throughout the 25-day monitoring period, the QDs were found to be properly dispersed in oil and free of aggregation in all samples. Values such as density and viscosity remained fairly constant due to the relatively low concentration ratio. However, an increase in total acid number was observed with increasing concentration. These results imply that QD-enhanced insulation oils may have applications in high-voltage applications in the future. The main innovation of this study lies in demonstrating that CdSeTe QDs can significantly enhance the dielectric strength of mineral oils while maintaining their essential physicochemical properties, offering a novel approach for improving insulation performance in high-voltage applications.</p></div>\",\"PeriodicalId\":653,\"journal\":{\"name\":\"Journal of Nanoparticle Research\",\"volume\":\"27 7\",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2025-07-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Nanoparticle Research\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11051-025-06389-w\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Nanoparticle Research","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11051-025-06389-w","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Mineral oils modified with CdSeTe QDs for improved stability and dielectric performance in high-voltage applications
This study explored the application of CdSeTe quantum dots (QDs) in mineral oils for high-voltage applications through a comprehensive approach. CdSeTe QDs were synthesized using an organometallic method and added to mineral oil at concentrations of 1 mg/L (C1), 5 mg/L (C2), and 10 mg/L (C3). The samples’ stability condition was monitored for a long period, and physicochemical tests were performed. Experimental results show that QD-modified oils have enhanced electrical properties compared to the base oil. The breakdown voltage was in the range of 17 to 23 kV for the base oil, while the breakdown voltage was in the range of 20 to 39 kV for the QD-modified (C2) insulating fluid sample. Throughout the 25-day monitoring period, the QDs were found to be properly dispersed in oil and free of aggregation in all samples. Values such as density and viscosity remained fairly constant due to the relatively low concentration ratio. However, an increase in total acid number was observed with increasing concentration. These results imply that QD-enhanced insulation oils may have applications in high-voltage applications in the future. The main innovation of this study lies in demonstrating that CdSeTe QDs can significantly enhance the dielectric strength of mineral oils while maintaining their essential physicochemical properties, offering a novel approach for improving insulation performance in high-voltage applications.
期刊介绍:
The objective of the Journal of Nanoparticle Research is to disseminate knowledge of the physical, chemical and biological phenomena and processes in structures that have at least one lengthscale ranging from molecular to approximately 100 nm (or submicron in some situations), and exhibit improved and novel properties that are a direct result of their small size.
Nanoparticle research is a key component of nanoscience, nanoengineering and nanotechnology.
The focus of the Journal is on the specific concepts, properties, phenomena, and processes related to particles, tubes, layers, macromolecules, clusters and other finite structures of the nanoscale size range. Synthesis, assembly, transport, reactivity, and stability of such structures are considered. Development of in-situ and ex-situ instrumentation for characterization of nanoparticles and their interfaces should be based on new principles for probing properties and phenomena not well understood at the nanometer scale. Modeling and simulation may include atom-based quantum mechanics; molecular dynamics; single-particle, multi-body and continuum based models; fractals; other methods suitable for modeling particle synthesis, assembling and interaction processes. Realization and application of systems, structures and devices with novel functions obtained via precursor nanoparticles is emphasized. Approaches may include gas-, liquid-, solid-, and vacuum-based processes, size reduction, chemical- and bio-self assembly. Contributions include utilization of nanoparticle systems for enhancing a phenomenon or process and particle assembling into hierarchical structures, as well as formulation and the administration of drugs. Synergistic approaches originating from different disciplines and technologies, and interaction between the research providers and users in this field, are encouraged.