{"title":"具有荧光蚊样复眼的超疏水复合微球的制备及性能研究","authors":"Deyu Yu, Liangjiong Yang, Qingsheng Deng, Haipeng Zou, Xinmei Yan, Zichen Zhang, Yan Jiang, Hongwen Zhang","doi":"10.1134/S0965545X25600516","DOIUrl":null,"url":null,"abstract":"<p>In this study, polysiloxane microspheres were prepared by silane hydrolysis condensation method, and polysiloxane microspheres with fluorescent properties were obtained after calcination. SiO<sub>2</sub> nanoparticles were synthesized by the template method and composited with fluorescent polysiloxane microspheres through surface modification, and superhydrophobic composite microspheres with fluorescent properties were successfully prepared. The composites constructed multi-scale micro-nanostructures with morphology and structure similar to mosquito compound eyes. The structure and properties of the composite microspheres were investigated using characterization tools such as Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and contact angle tester. The results showed that the SiO<sub>2</sub> nanoparticles were successfully compounded with polysiloxane microspheres and formed a stable structure; the surface of the composite microspheres showed superhydrophobicity while retaining the fluorescent properties of the polysiloxane matrix. This fluorescent superhydrophobic composite with a bionic compound eye structure has broad application prospects in the fields of optical devices and functional coatings, etc.</p>","PeriodicalId":738,"journal":{"name":"Polymer Science, Series A","volume":"66 6","pages":"730 - 738"},"PeriodicalIF":1.1000,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation and Properties of Superhydrophobic Composite Microspheres with Fluorescent Mosquito-Like Compound Eyes\",\"authors\":\"Deyu Yu, Liangjiong Yang, Qingsheng Deng, Haipeng Zou, Xinmei Yan, Zichen Zhang, Yan Jiang, Hongwen Zhang\",\"doi\":\"10.1134/S0965545X25600516\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this study, polysiloxane microspheres were prepared by silane hydrolysis condensation method, and polysiloxane microspheres with fluorescent properties were obtained after calcination. SiO<sub>2</sub> nanoparticles were synthesized by the template method and composited with fluorescent polysiloxane microspheres through surface modification, and superhydrophobic composite microspheres with fluorescent properties were successfully prepared. The composites constructed multi-scale micro-nanostructures with morphology and structure similar to mosquito compound eyes. The structure and properties of the composite microspheres were investigated using characterization tools such as Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and contact angle tester. The results showed that the SiO<sub>2</sub> nanoparticles were successfully compounded with polysiloxane microspheres and formed a stable structure; the surface of the composite microspheres showed superhydrophobicity while retaining the fluorescent properties of the polysiloxane matrix. This fluorescent superhydrophobic composite with a bionic compound eye structure has broad application prospects in the fields of optical devices and functional coatings, etc.</p>\",\"PeriodicalId\":738,\"journal\":{\"name\":\"Polymer Science, Series A\",\"volume\":\"66 6\",\"pages\":\"730 - 738\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2025-07-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Science, Series A\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0965545X25600516\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series A","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S0965545X25600516","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Preparation and Properties of Superhydrophobic Composite Microspheres with Fluorescent Mosquito-Like Compound Eyes
In this study, polysiloxane microspheres were prepared by silane hydrolysis condensation method, and polysiloxane microspheres with fluorescent properties were obtained after calcination. SiO2 nanoparticles were synthesized by the template method and composited with fluorescent polysiloxane microspheres through surface modification, and superhydrophobic composite microspheres with fluorescent properties were successfully prepared. The composites constructed multi-scale micro-nanostructures with morphology and structure similar to mosquito compound eyes. The structure and properties of the composite microspheres were investigated using characterization tools such as Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and contact angle tester. The results showed that the SiO2 nanoparticles were successfully compounded with polysiloxane microspheres and formed a stable structure; the surface of the composite microspheres showed superhydrophobicity while retaining the fluorescent properties of the polysiloxane matrix. This fluorescent superhydrophobic composite with a bionic compound eye structure has broad application prospects in the fields of optical devices and functional coatings, etc.
期刊介绍:
Polymer Science, Series A is a journal published in collaboration with the Russian Academy of Sciences. Series A includes experimental and theoretical papers and reviews devoted to physicochemical studies of the structure and properties of polymers (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed. Online submission via Internet to the Series A, B, and C is available at http://polymsci.ru.