LiFePO4正极材料的合成与制备研究进展

IF 2.6 4区 化学 Q3 CHEMISTRY, PHYSICAL
Ionics Pub Date : 2025-06-13 DOI:10.1007/s11581-025-06460-5
Anisa Surya Wijareni, Jotti Karunawan, Zela Tanlega Ichlas, Afriyanti Sumboja, Mohammad Zaki Mubarok
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引用次数: 0

摘要

磷酸铁锂(LiFePO4/LFP)电池具有巨大的潜力,将对电动汽车市场产生重大影响。这些电池是用锂、铁和磷酸盐作为前体合成的。它们具有多种优势,如丰富的可用性、低毒性、高热稳定性和成本效益,使其成为电动汽车应用的一个有吸引力的选择。然而,LFP电池的广泛采用面临着一些挑战,包括合适的前体的有限可用性以及需要更优化的制造工艺以确保一致和高效的性能。因此,彻底了解LFP电池的制造过程是必不可少的。本文旨在全面了解各种铁源的合成路线及其在LFP电池生产中的适用性。这些合成工艺包括水热法、喷雾热解法、溶胶-凝胶法、固态法、干乳法、微波加热法、碳热法、机械化学活化法、共沉淀法等多种合成方法。每种方法在效率、所得材料的质量以及与可用铁源的兼容性方面都具有特定的优点和缺点。通过探索和优化合适的制造方法,我们可以克服阻碍LFP电池发展的关键挑战,提高其容量和循环寿命,并加速其在全球电动汽车市场的应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Recent advances in synthesis and fabrication of LiFePO4 cathode materials: a comprehensive review

Lithium iron phosphate (LiFePO4/LFP) batteries have great potential to significantly impact the electric vehicle market. These batteries are synthesized using lithium, iron, and phosphate as precursors. They offer several advantages, such as abundant availability, low toxicity, high thermal stability, and cost-effectiveness, making them an attractive option for electric vehicle applications. However, the widespread adoption of LFP batteries faces several challenges, including the limited availability of suitable precursors and the need for a more optimized fabrication process to ensure consistent and efficient performance. Therefore, a thorough understanding of the LFP battery fabrication process is essential. This paper aims to comprehensively understand the synthesis routes and suitability of various iron sources for LFP battery production. These synthesis processes include various synthesis methods such as hydrothermal, spray pyrolysis, sol-gel, solid-state, dry emulsion, microwave heating, carbothermal, mechanochemical activation, and coprecipitation. Each method offers specific advantages and disadvantages regarding efficiency, quality of the resulting material, and compatibility with the available iron source. By exploring and optimizing appropriate fabrication methods, we can overcome the key challenges hindering the development of LFP batteries, increase their capacity and cycle life, and accelerate their adoption in the global electric vehicle market.

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来源期刊
Ionics
Ionics 化学-电化学
CiteScore
5.30
自引率
7.10%
发文量
427
审稿时长
2.2 months
期刊介绍: Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.
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