1h -吲哚-3-乙酸硅基衍生物的合成

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2025-07-10 DOI:10.1007/s11172-024-4675-y

A. S. Soldatenko, A. I. Albanov, N. F. Lazareva

引用次数: 0

摘要

以1h -吲哚-3-乙酸为原料，与六甲基二矽氮烷、Me3SiCl和ClCH2SiMe2Cl进行硅基化反应，合成了（1-三甲基硅基- 1h -吲哚-3-基）乙酸三甲基硅基、（氯甲基）（二甲基）硅基（1h -吲哚-3-基）乙酸和（氯甲基）（二甲基）硅基[1-（氯甲基）（二甲基）-硅基- 1h -吲哚-3-基]乙酸。所得化合物的结构经多核磁共振波谱和红外光谱确证。

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Synthesis of silyl derivatives of 1H-indole-3-acetic acid

Trimethylsilyl (1-trimethylsilyl-1H-indol-3-yl)acetate, (chloromethyl)(dimethyl)silyl (1H-indol-3-yl)acetate, and (chloromethyl)(dimethyl)silyl [1-(chloromethyl)(dimethyl)-silyl-1H-indol-3-yl]acetate were synthesized by silylation of 1H-indole-3-acetic acid with hexamethyldisilazane, Me₃SiCl, and ClCH₂SiMe₂Cl. The structures of obtained compounds were confirmed by multinuclear NMR spectroscopy and IR spectroscopy.

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.