过渡金属催化电石反应的研究进展及展望

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2025-07-10 DOI:10.1007/s11172-024-4649-0

Yu. V. Gyrdymova, A. N. Potorochenko

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引用次数: 0

摘要

本文系统总结了过渡金属催化电石化学转化的研究进展。CaC2的成功应用被证明可以得到单取代和双取代炔，以及各种杂环化合物，特别是具有重要药用价值的三唑和咪唑。电石是发展以碳中性循环为基础的有机合成的方便试剂。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Reactions of calcium carbide catalyzed by transition metals: recent advances and prospects

The review systematizes and summarizes information on chemical transformations of calcium carbide catalyzed by transition metals. The successful application of CaC₂ was demonstrated for obtaining mono- and disubstituted alkynes, a wide range of heterocyclic compounds, in particular pharmaceutically important triazoles and imidazoles. Calcium carbide is a convenient reagent for development of organic syntheses based on a carbon-neutral cycle.

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.