CsCdCl3:Mn2+荧光粉易于相位调谐,可获得近统一量子产率和延长余辉

IF 7.4 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Yeqi Liu  (, ), Xiangzhou Zhang  (, ), Jun Wei  (, ), Xiaojia Wang  (, ), Yuhai Zhang  (, )
{"title":"CsCdCl3:Mn2+荧光粉易于相位调谐,可获得近统一量子产率和延长余辉","authors":"Yeqi Liu \n (,&nbsp;),&nbsp;Xiangzhou Zhang \n (,&nbsp;),&nbsp;Jun Wei \n (,&nbsp;),&nbsp;Xiaojia Wang \n (,&nbsp;),&nbsp;Yuhai Zhang \n (,&nbsp;)","doi":"10.1007/s40843-025-3442-0","DOIUrl":null,"url":null,"abstract":"<div><p>While the hexagonal-phase CsCdCl<sub>3</sub> was extensively reported due to its high photoluminescence quantum yield and ultralong afterglow duration, the cubic-phase CsCdCl<sub>3</sub> remained elusive. Herein, the cubic-phase CsCdCl<sub>3</sub> microcrystals were synthesized via a solid-state synthesis at room temperature. After 10%-Mn<sup>2+</sup> doping, the photo-luminescence quantum yield (PL QY) was improved to near unity and the afterglow duration was extended to 10 h. Importantly, the cubic phase was found meta-stable toward thermal treatment, where a transition to hexagonal phase was observed upon heating at 100 °C. In addition, the phase transition was also sensitive to Mn<sup>2+</sup>-doping concentration, which provided a facile tool to manipulate the lattice structure of octahedra dimers (hexagonal) or monomers (cubic). The mechanism of phase transition was theoretically explained through both phonon spectrum and lattice formation energy. This work opened many avenues to advanced applications such as information storage, X-ray imaging and anti-counterfeiting.</p></div>","PeriodicalId":773,"journal":{"name":"Science China Materials","volume":"68 8","pages":"2735 - 2741"},"PeriodicalIF":7.4000,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Facile phase tuning of CsCdCl3:Mn2+ phosphor for nearly-unity quantum yield and extended afterglow\",\"authors\":\"Yeqi Liu \\n (,&nbsp;),&nbsp;Xiangzhou Zhang \\n (,&nbsp;),&nbsp;Jun Wei \\n (,&nbsp;),&nbsp;Xiaojia Wang \\n (,&nbsp;),&nbsp;Yuhai Zhang \\n (,&nbsp;)\",\"doi\":\"10.1007/s40843-025-3442-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>While the hexagonal-phase CsCdCl<sub>3</sub> was extensively reported due to its high photoluminescence quantum yield and ultralong afterglow duration, the cubic-phase CsCdCl<sub>3</sub> remained elusive. Herein, the cubic-phase CsCdCl<sub>3</sub> microcrystals were synthesized via a solid-state synthesis at room temperature. After 10%-Mn<sup>2+</sup> doping, the photo-luminescence quantum yield (PL QY) was improved to near unity and the afterglow duration was extended to 10 h. Importantly, the cubic phase was found meta-stable toward thermal treatment, where a transition to hexagonal phase was observed upon heating at 100 °C. In addition, the phase transition was also sensitive to Mn<sup>2+</sup>-doping concentration, which provided a facile tool to manipulate the lattice structure of octahedra dimers (hexagonal) or monomers (cubic). The mechanism of phase transition was theoretically explained through both phonon spectrum and lattice formation energy. This work opened many avenues to advanced applications such as information storage, X-ray imaging and anti-counterfeiting.</p></div>\",\"PeriodicalId\":773,\"journal\":{\"name\":\"Science China Materials\",\"volume\":\"68 8\",\"pages\":\"2735 - 2741\"},\"PeriodicalIF\":7.4000,\"publicationDate\":\"2025-07-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Science China Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s40843-025-3442-0\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science China Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s40843-025-3442-0","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

虽然六方相CsCdCl3因其高光致发光量子产率和超长余辉持续时间而被广泛报道,但三相CsCdCl3仍未被广泛报道。本文采用室温固相法合成了三相CsCdCl3微晶体。10%-Mn2+掺杂后,光致发光量子产率(PL QY)提高到接近统一,余辉持续时间延长到10 h。重要的是,立方体相在热处理过程中表现出亚稳定,在100°C加热时观察到向六方相的转变。此外,相变对Mn2+掺杂浓度也很敏感,这为操纵八面体二聚体(六边形)或单体(立方)的晶格结构提供了方便的工具。从声子谱和晶格形成能两个方面对相变机理进行了理论解释。这项工作为信息存储、x射线成像和防伪等先进应用开辟了许多途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Facile phase tuning of CsCdCl3:Mn2+ phosphor for nearly-unity quantum yield and extended afterglow

While the hexagonal-phase CsCdCl3 was extensively reported due to its high photoluminescence quantum yield and ultralong afterglow duration, the cubic-phase CsCdCl3 remained elusive. Herein, the cubic-phase CsCdCl3 microcrystals were synthesized via a solid-state synthesis at room temperature. After 10%-Mn2+ doping, the photo-luminescence quantum yield (PL QY) was improved to near unity and the afterglow duration was extended to 10 h. Importantly, the cubic phase was found meta-stable toward thermal treatment, where a transition to hexagonal phase was observed upon heating at 100 °C. In addition, the phase transition was also sensitive to Mn2+-doping concentration, which provided a facile tool to manipulate the lattice structure of octahedra dimers (hexagonal) or monomers (cubic). The mechanism of phase transition was theoretically explained through both phonon spectrum and lattice formation energy. This work opened many avenues to advanced applications such as information storage, X-ray imaging and anti-counterfeiting.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Science China Materials
Science China Materials Materials Science-General Materials Science
CiteScore
11.40
自引率
7.40%
发文量
949
期刊介绍: Science China Materials (SCM) is a globally peer-reviewed journal that covers all facets of materials science. It is supervised by the Chinese Academy of Sciences and co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China. The journal is jointly published monthly in both printed and electronic forms by Science China Press and Springer. The aim of SCM is to encourage communication of high-quality, innovative research results at the cutting-edge interface of materials science with chemistry, physics, biology, and engineering. It focuses on breakthroughs from around the world and aims to become a world-leading academic journal for materials science.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信