具有优异的透明度和抗菌性能的金属化聚合物刷状涂层

IF 4.5 3区 工程技术 Q2 ENGINEERING, CHEMICAL
Ling Yin, Shengfei Li, Yuxiang Zhao, Guangen Fu, Haoyong Yang, Daheng Wu, Jianing Wang, Tao Zhang
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引用次数: 0

摘要

具有可控性能和纳米级厚度的表面接枝聚合物刷是防止生物污染的透明涂层的理想候选者。然而,在自然环境中保持长期抗菌性能仍然是一个重大挑战。在这项研究中,我们提出了一种金属化聚合物刷(Mt-PB)涂层,它结合了优异的透明度和抗菌性能。该涂层是通过协同原位还原将过渡金属离子(例如Cu和Ag)加入表面接枝的聚合物刷中制备的。由于金属化刷层超薄(Cu-PB, ~ 60.07 nm; Ag-PB, ~ 57.45 nm),所得到的涂层具有高透光率(~ 86%)和优异的抗菌效率(对大肠杆菌和金黄色葡萄球菌的抑制率~ 99.99%)。此外,mt - pb涂层的镜头具有出色的抗菌和防污耐久性,水下检测测试证明,在水下暴露一个多月的情况下,可以提供高分辨率图像和稳定的透明度(Δ < 2%)。这些发现为开发适用于水下光学器件的透明防污涂层提供了一个有希望的策略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Metalated polymer brush coatings with excellent transparence and antibacterial properties

Surface-grafted polymer brushes with controlled properties and nanoscale thickness are ideal candidates for transparent coatings to prevent biofouling. However, maintaining long-term antibacterial performance in natural environments remains a significant challenge. In this study, we present a metalated polymer brush (Mt-PB) coating that combines excellent transparency with antimicrobial properties. The coating is prepared by incorporating transition metal ions (e.g., Cu and Ag) into surface-grafted polymer brushes through cooperative in situ reduction. Due to the ultra-thinness of the metalated brush layer (Cu-PB, ∼60.07 nm; Ag-PB, ∼57.45 nm), the resulting coating exhibits high optical transmittance (∼86%) and superior antibacterial efficiency (∼99.99% inhibition rate against E. coli and S. aureus). Additionally, the Mt-PB-coated lens demonstrates excellent antibacterial and antifouling durability, as evidenced by underwater detection tests that provide high-resolution images and stable transparency (Δ < 2%) for over a month of underwater exposure. These findings offer a promising strategy for developing transparent and antifouling coatings suitable for underwater optical devices.

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来源期刊
CiteScore
7.60
自引率
6.70%
发文量
868
审稿时长
1 months
期刊介绍: Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.
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