测定复合热固性聚合物固化现象的逆分析

IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES
Bilen Emek Abali, Reza Afshar, Christos Athanasopoulos, Francisco Penayo
{"title":"测定复合热固性聚合物固化现象的逆分析","authors":"Bilen Emek Abali,&nbsp;Reza Afshar,&nbsp;Christos Athanasopoulos,&nbsp;Francisco Penayo","doi":"10.1007/s10443-025-10352-2","DOIUrl":null,"url":null,"abstract":"<div><p>Curing is a reaction leading to a hardened material in mixtures of two or more components known as themosetting polymers. The specific choice of components allows to regulate the speed of reaction. In some applications, fast kinetics are chosen to achieve a fully hardened product within seconds. Yet in other applications, where the mixture is cast in larger volumes, a slower curing rate is needed to allow the cast or mold process to be completed before significant hardening has been occurred. Specifically in the latter case, such a reaction is of importance to model accurately; yet an interplay of several mechanisms makes it challenging to predict the correct model to be used in curing. Such a polymer comprising multiple components has been analyzed by listing different models available. Based on them, a phenomenological model is proposed that resembles a slowly reacting thermosetting polymer. An inverse analysis approach is developed for acquiring a fit representing the data with a good agreement.</p></div>","PeriodicalId":468,"journal":{"name":"Applied Composite Materials","volume":"32 4","pages":"1351 - 1363"},"PeriodicalIF":2.9000,"publicationDate":"2025-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10443-025-10352-2.pdf","citationCount":"0","resultStr":"{\"title\":\"Inverse Analysis for Determining Curing Phenomenon in Composite Thermosetting Polymers\",\"authors\":\"Bilen Emek Abali,&nbsp;Reza Afshar,&nbsp;Christos Athanasopoulos,&nbsp;Francisco Penayo\",\"doi\":\"10.1007/s10443-025-10352-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Curing is a reaction leading to a hardened material in mixtures of two or more components known as themosetting polymers. The specific choice of components allows to regulate the speed of reaction. In some applications, fast kinetics are chosen to achieve a fully hardened product within seconds. Yet in other applications, where the mixture is cast in larger volumes, a slower curing rate is needed to allow the cast or mold process to be completed before significant hardening has been occurred. Specifically in the latter case, such a reaction is of importance to model accurately; yet an interplay of several mechanisms makes it challenging to predict the correct model to be used in curing. Such a polymer comprising multiple components has been analyzed by listing different models available. Based on them, a phenomenological model is proposed that resembles a slowly reacting thermosetting polymer. An inverse analysis approach is developed for acquiring a fit representing the data with a good agreement.</p></div>\",\"PeriodicalId\":468,\"journal\":{\"name\":\"Applied Composite Materials\",\"volume\":\"32 4\",\"pages\":\"1351 - 1363\"},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2025-06-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s10443-025-10352-2.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Composite Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10443-025-10352-2\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Composite Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10443-025-10352-2","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
引用次数: 0

摘要

固化是一种反应,导致两种或两种以上称为热固性聚合物的成分的混合物硬化的材料。组件的特定选择允许调节反应速度。在某些应用中,选择快速动力学以在几秒钟内实现完全硬化的产品。然而,在其他应用中,当混合物以较大的体积浇铸时,需要较慢的固化速度,以便在发生明显硬化之前完成浇铸或模具过程。具体地说,在后一种情况下,这种反应对于准确地建模很重要;然而,几种机制的相互作用使得预测在固化中使用的正确模型具有挑战性。这种由多种组分组成的聚合物已经通过列出不同的模型进行了分析。在此基础上,提出了一个类似于慢反应热固性聚合物的现象学模型。提出了一种逆分析方法,以获得具有良好一致性的数据的拟合。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Inverse Analysis for Determining Curing Phenomenon in Composite Thermosetting Polymers

Curing is a reaction leading to a hardened material in mixtures of two or more components known as themosetting polymers. The specific choice of components allows to regulate the speed of reaction. In some applications, fast kinetics are chosen to achieve a fully hardened product within seconds. Yet in other applications, where the mixture is cast in larger volumes, a slower curing rate is needed to allow the cast or mold process to be completed before significant hardening has been occurred. Specifically in the latter case, such a reaction is of importance to model accurately; yet an interplay of several mechanisms makes it challenging to predict the correct model to be used in curing. Such a polymer comprising multiple components has been analyzed by listing different models available. Based on them, a phenomenological model is proposed that resembles a slowly reacting thermosetting polymer. An inverse analysis approach is developed for acquiring a fit representing the data with a good agreement.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Applied Composite Materials
Applied Composite Materials 工程技术-材料科学:复合
CiteScore
4.20
自引率
4.30%
发文量
81
审稿时长
1.6 months
期刊介绍: Applied Composite Materials is an international journal dedicated to the publication of original full-length papers, review articles and short communications of the highest quality that advance the development and application of engineering composite materials. Its articles identify problems that limit the performance and reliability of the composite material and composite part; and propose solutions that lead to innovation in design and the successful exploitation and commercialization of composite materials across the widest spectrum of engineering uses. The main focus is on the quantitative descriptions of material systems and processing routes. Coverage includes management of time-dependent changes in microscopic and macroscopic structure and its exploitation from the material''s conception through to its eventual obsolescence.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信