物理力学性能对乙丙二烯基隧道管片垫片水密性能的影响

IF 2.8 3区 化学 Q3 POLYMER SCIENCE
Ekrem Altuncu, Nevcan Ince Baysal, Nilay Tuccar Kilic
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引用次数: 0

摘要

水密性是隧道施工和运营过程中的一个重要问题。在工业上,乙丙二烯单体(EPDM)衬垫通常用于隧道接缝,以防止地下水渗入。本文研究了三元乙丙橡胶(EPDM)节段垫片的物理力学性能,特别是填料含量对其防水性能的影响。以炭黑(CB)和碳酸钙(CaCO3)为填料,采用内部混频器和热压法制备EPDM化合物,并进行了各种物理、机械、形态和水密性测试。合金的硬度范围为68 ~ 71 Shore A,密度范围为1.16 ~ 1.28±0.04 g/cm3,不同填料量对合金的硬度变化不显著。然而,随着填料负荷的增加,拉伸强度从12.7 MPa下降到6.3 MPa,断裂伸长率从415%下降到294%。随着填料含量的增加,压缩率从9.7%提高到49.6%。应力松弛试验表明,当填料含量超过50%时,应力损失增加,填料含量越少,性能越好。水密性试验表明,填料含量较低的化合物可以承受高达28 bar的水压,偏移量为6 mm,而填料含量较高的化合物只能承受10 bar的水压,偏移量为2 mm。形态分析表明,在填料含量较低的化合物中,其分布更为均匀。因此,填料含量较低的EPDM-CB-CaCO3化合物可优选用于隧道节段接缝,以改善其水密性和力学性能。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effects of the physico-mechanical properties on water tightness performance of ethylene propylene diene monomer-based tunnel segment gasket

Water tightness is a critical concern for tunnels during both construction and operation. In industry, ethylene propylene diene monomer (EPDM) gaskets are commonly used at tunnel joints to prevent groundwater infiltration. This study investigates the influence of physical and mechanical properties, particularly about filler content, on the waterproofing performance of EPDM segmental gaskets. EPDM compounds with carbon black (CB) and calcium carbonate (CaCO3) fillers were prepared using an internal mixer and hot press, followed by various physical, mechanical, morphological, and water-tightness tests. The hardness of the compounds ranged from 68 to 71 Shore A, while densities varied from 1.16 to 1.28 ± 0.04 g/cm3, indicating no significant change with different filler amounts. However, tensile strength decreased from 12.7 to 6.3 MPa, and elongation-at-break values dropped from 415 to 294% as filler loading increased. Compression sets rose from 9.7% to 49.6% with higher filler content. Stress-relaxation tests revealed that stress losses increased when filler quantities exceeded 50%, with formulations containing less filler exhibiting superior performance. Water-tightness tests showed that the compound with lower filler content could withstand up to 28 bar of water pressure with a 6 mm offset, while the compound with higher filler content only tolerated 10 bar with a 2 mm offset. Morphological analysis indicated a more homogeneous distribution in compounds with lower levels of fillers. Therefore, EPDM–CB–CaCO3 compounds with lower filler content may be preferred in tunnel segmental joints, offering improved water tightness and mechanical performance.

Graphical Abstract

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来源期刊
Iranian Polymer Journal
Iranian Polymer Journal 化学-高分子科学
CiteScore
4.90
自引率
9.70%
发文量
107
审稿时长
2.8 months
期刊介绍: Iranian Polymer Journal, a monthly peer-reviewed international journal, provides a continuous forum for the dissemination of the original research and latest advances made in science and technology of polymers, covering diverse areas of polymer synthesis, characterization, polymer physics, rubber, plastics and composites, processing and engineering, biopolymers, drug delivery systems and natural polymers to meet specific applications. Also contributions from nano-related fields are regarded especially important for its versatility in modern scientific development.
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