Yasin Khani, Kanghee Cho, Kwang-Eun Jeong, Chul-Ung Kim, Young-Kwon Park
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引用次数: 0
摘要
本研究评价了Ni-X-AlSBA-15 (X = Y, Sm, Gd和La)催化剂在乙烯低聚过程中的性能。考察了Y、Sm、Gd和La启动子对乙烯低聚反应的影响。与Ni-AlSBA-15相比,Ni-X-AlSBA-15 (X = Y, Sm, Gd和La)催化剂的催化活性和选择性显著提高。特别是,Ni-Gd-AlSBA-15催化剂在运行12小时后,乙烯转化为丁烯的转化率最高(50.0 wt.%)。这些增强是由于活性位点的分散改善,氧空位的存在,以及酸和Ni位点的优化密度,这些共同提高了乙烯分子的吸附速率。丁烯的选择性提高(≥80%)证实了钆作为促进剂对催化活性有积极的影响。总的来说,Gd启动子加上AlSBA-15在ni基催化剂中的显著优势,有望通过乙烯低聚生成丁烯。
Catalytic Ethylene Oligomerization over Ni-Loaded X-AlSBA-15 (X = Gd, Y, La, and Sm) Catalysts
This study evaluated the performance of Ni-X-AlSBA-15 (X = Y, Sm, Gd, and La) catalysts in the ethylene oligomerization processes. The effects of Y, Sm, Gd, and La promoters on the ethylene oligomerization process were examined. The Ni-X-AlSBA-15 (X = Y, Sm, Gd, and La) catalysts demonstrated a considerably enhanced catalytic activity and selectivity compared with that of Ni-AlSBA-15. In particular, the Ni-Gd-AlSBA-15 catalyst achieved the highest conversion of ethylene to butene (50.0 wt.%) after 12 h of time on stream. These enhancements were attributed to the improved dispersion of active sites, the presence of oxygen vacancies, and the optimized densities of the acid and Ni sites, which collectively enhanced the rate of adsorption of ethylene molecules. An increase in the selectivity of butylene (≥ 80%) confirmed that the gadolinium as a promoter had a positive effect on the catalytic activity. Overall, the Gd promoter, coupled with the remarkable benefits of AlSBA-15 in Ni-based catalysts, is promising for butene generation through ethylene oligomerization.
期刊介绍:
The Korean Journal of Chemical Engineering provides a global forum for the dissemination of research in chemical engineering. The Journal publishes significant research results obtained in the Asia-Pacific region, and simultaneously introduces recent technical progress made in other areas of the world to this region. Submitted research papers must be of potential industrial significance and specifically concerned with chemical engineering. The editors will give preference to papers having a clearly stated practical scope and applicability in the areas of chemical engineering, and to those where new theoretical concepts are supported by new experimental details. The Journal also regularly publishes featured reviews on emerging and industrially important subjects of chemical engineering as well as selected papers presented at international conferences on the subjects.