Luyu Zheng, Mei Wu, Dayu Sun, Wei Zhao, Qingzhong Xue, Liang Song, Qing Yu, Haodong Duan, Hui Yang, Zhongwei Wang
{"title":"基于二苯基氧化膦衍生物的高玻璃化温度和高透明度阻燃环氧树脂的研制","authors":"Luyu Zheng, Mei Wu, Dayu Sun, Wei Zhao, Qingzhong Xue, Liang Song, Qing Yu, Haodong Duan, Hui Yang, Zhongwei Wang","doi":"10.1007/s11705-025-2575-9","DOIUrl":null,"url":null,"abstract":"<div><p>To obtain high-performance flame-retardant epoxy resin (EP), diglycidyl ether of (2,5-dihydroxyphenyl) diphenyl phosphine oxide (DPO-HQ-EP) was synthesized. EP/DPO-HQ-EP samples with varying phosphorus contents were prepared by curing a mixture of DPO-HQ-EP and diglycidyl ether of bisphenol A. The incorporation of DPO-HQ-EP significantly enhanced the flame retardancy of EP without compromising its glass transition temperature. The EP/DPO-HQ-EP/0.6 exhibited a limited oxygen index of 31.7% and achieved a V-0 rating in the vertical burning test. In the cone calorimeter test, due to the incorporation of DPO-HQ-EP, the peak of heat release rate and total heat release of EP/DPO-HQ-EP/0.6 decreased by 39.4% and 15.9% compared with the values for pure EP. A detailed investigation of the flame-retardant mechanism revealed that the improved flame retardancy of EP/DPO-HQ-EP samples was attributed to the release of phosphorus-containing free radicals and non-flammable gases in the gas phase, as well as the formation of a continuous and dense char layer in the condensed phase. Moreover, the dielectric constant and dielectric loss factor of EP/DPO-HQ-EP samples were lower than those of EP/0. The water absorptivity and transparency of EP were effectively preserved with the incorporation of DPO-HQ-EP. These findings highlighted the potential of EP/DPO-HQ-EP for industrial applications in an electrical field.\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"19 8","pages":""},"PeriodicalIF":4.5000,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development of a flame-retardant epoxy resin with high glass transition temperature and transparency based on a diphenylphosphine oxide derivative\",\"authors\":\"Luyu Zheng, Mei Wu, Dayu Sun, Wei Zhao, Qingzhong Xue, Liang Song, Qing Yu, Haodong Duan, Hui Yang, Zhongwei Wang\",\"doi\":\"10.1007/s11705-025-2575-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>To obtain high-performance flame-retardant epoxy resin (EP), diglycidyl ether of (2,5-dihydroxyphenyl) diphenyl phosphine oxide (DPO-HQ-EP) was synthesized. EP/DPO-HQ-EP samples with varying phosphorus contents were prepared by curing a mixture of DPO-HQ-EP and diglycidyl ether of bisphenol A. The incorporation of DPO-HQ-EP significantly enhanced the flame retardancy of EP without compromising its glass transition temperature. The EP/DPO-HQ-EP/0.6 exhibited a limited oxygen index of 31.7% and achieved a V-0 rating in the vertical burning test. In the cone calorimeter test, due to the incorporation of DPO-HQ-EP, the peak of heat release rate and total heat release of EP/DPO-HQ-EP/0.6 decreased by 39.4% and 15.9% compared with the values for pure EP. A detailed investigation of the flame-retardant mechanism revealed that the improved flame retardancy of EP/DPO-HQ-EP samples was attributed to the release of phosphorus-containing free radicals and non-flammable gases in the gas phase, as well as the formation of a continuous and dense char layer in the condensed phase. Moreover, the dielectric constant and dielectric loss factor of EP/DPO-HQ-EP samples were lower than those of EP/0. The water absorptivity and transparency of EP were effectively preserved with the incorporation of DPO-HQ-EP. 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Development of a flame-retardant epoxy resin with high glass transition temperature and transparency based on a diphenylphosphine oxide derivative
To obtain high-performance flame-retardant epoxy resin (EP), diglycidyl ether of (2,5-dihydroxyphenyl) diphenyl phosphine oxide (DPO-HQ-EP) was synthesized. EP/DPO-HQ-EP samples with varying phosphorus contents were prepared by curing a mixture of DPO-HQ-EP and diglycidyl ether of bisphenol A. The incorporation of DPO-HQ-EP significantly enhanced the flame retardancy of EP without compromising its glass transition temperature. The EP/DPO-HQ-EP/0.6 exhibited a limited oxygen index of 31.7% and achieved a V-0 rating in the vertical burning test. In the cone calorimeter test, due to the incorporation of DPO-HQ-EP, the peak of heat release rate and total heat release of EP/DPO-HQ-EP/0.6 decreased by 39.4% and 15.9% compared with the values for pure EP. A detailed investigation of the flame-retardant mechanism revealed that the improved flame retardancy of EP/DPO-HQ-EP samples was attributed to the release of phosphorus-containing free radicals and non-flammable gases in the gas phase, as well as the formation of a continuous and dense char layer in the condensed phase. Moreover, the dielectric constant and dielectric loss factor of EP/DPO-HQ-EP samples were lower than those of EP/0. The water absorptivity and transparency of EP were effectively preserved with the incorporation of DPO-HQ-EP. These findings highlighted the potential of EP/DPO-HQ-EP for industrial applications in an electrical field.
期刊介绍:
Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.