Jinbo Song, Jieying Jing, Jinpeng Zhang, Yufeng Xu, Wen-Ying Li
{"title":"碱金属盐促进MgO吸附剂的造粒机理及CO2捕集性能","authors":"Jinbo Song, Jieying Jing, Jinpeng Zhang, Yufeng Xu, Wen-Ying Li","doi":"10.1007/s11705-025-2576-8","DOIUrl":null,"url":null,"abstract":"<div><p>Alkaline metal salt-promoted MgO sorbents are effective for CO<sub>2</sub> capture, but they face challenges with decreased CO<sub>2</sub> capture performance and powder elutriation in practical applications, arising due to the loss of pore structures and poor mechanical strength of alkaline metal salt-promoted MgO sorbent powder. Herein, granulation technology was employed to resolve the above problem. The optimized alkaline metal salt-promoted MgO sorbent pellets exhibited a CO<sub>2</sub> capture capacity of 11.46 mmol·g<sup>−1</sup> and a mechanical strength of 11.14 MPa. This mechanical strength was nearly three times greater than that of alkaline metal salt-promoted MgO sorbent pellets without granulation promoters. After 20 cycles, CO<sub>2</sub> capture capacity stabilized at 8.71 mmol·g<sup>−1</sup>, while mechanical strength was maintained at 8.92 MPa. Through characterization, it was revealed that the pore structure generated by the pyrolysis of the granulation promoters notably increased the specific surface area, leading to high CO<sub>2</sub> capture capacity. Meanwhile, the strengthened mechanical strength of the alkaline metal salt-promoted MgO sorbent pellets was primarily due to the <i>in situ</i> formation of a <i>γ</i>-AlOOH sol-gel cluster skeleton. Thus, this study provides an effective technological pathway to enhance the performance of the alkaline metal salt-promoted MgO sorbent pellets for industrial applications.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"19 12","pages":""},"PeriodicalIF":4.5000,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Granulation mechanism and CO2 capture performance of alkaline metal salt-promoted MgO sorbents\",\"authors\":\"Jinbo Song, Jieying Jing, Jinpeng Zhang, Yufeng Xu, Wen-Ying Li\",\"doi\":\"10.1007/s11705-025-2576-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Alkaline metal salt-promoted MgO sorbents are effective for CO<sub>2</sub> capture, but they face challenges with decreased CO<sub>2</sub> capture performance and powder elutriation in practical applications, arising due to the loss of pore structures and poor mechanical strength of alkaline metal salt-promoted MgO sorbent powder. Herein, granulation technology was employed to resolve the above problem. The optimized alkaline metal salt-promoted MgO sorbent pellets exhibited a CO<sub>2</sub> capture capacity of 11.46 mmol·g<sup>−1</sup> and a mechanical strength of 11.14 MPa. This mechanical strength was nearly three times greater than that of alkaline metal salt-promoted MgO sorbent pellets without granulation promoters. After 20 cycles, CO<sub>2</sub> capture capacity stabilized at 8.71 mmol·g<sup>−1</sup>, while mechanical strength was maintained at 8.92 MPa. Through characterization, it was revealed that the pore structure generated by the pyrolysis of the granulation promoters notably increased the specific surface area, leading to high CO<sub>2</sub> capture capacity. Meanwhile, the strengthened mechanical strength of the alkaline metal salt-promoted MgO sorbent pellets was primarily due to the <i>in situ</i> formation of a <i>γ</i>-AlOOH sol-gel cluster skeleton. Thus, this study provides an effective technological pathway to enhance the performance of the alkaline metal salt-promoted MgO sorbent pellets for industrial applications.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":571,\"journal\":{\"name\":\"Frontiers of Chemical Science and Engineering\",\"volume\":\"19 12\",\"pages\":\"\"},\"PeriodicalIF\":4.5000,\"publicationDate\":\"2025-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Frontiers of Chemical Science and Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11705-025-2576-8\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers of Chemical Science and Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11705-025-2576-8","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Granulation mechanism and CO2 capture performance of alkaline metal salt-promoted MgO sorbents
Alkaline metal salt-promoted MgO sorbents are effective for CO2 capture, but they face challenges with decreased CO2 capture performance and powder elutriation in practical applications, arising due to the loss of pore structures and poor mechanical strength of alkaline metal salt-promoted MgO sorbent powder. Herein, granulation technology was employed to resolve the above problem. The optimized alkaline metal salt-promoted MgO sorbent pellets exhibited a CO2 capture capacity of 11.46 mmol·g−1 and a mechanical strength of 11.14 MPa. This mechanical strength was nearly three times greater than that of alkaline metal salt-promoted MgO sorbent pellets without granulation promoters. After 20 cycles, CO2 capture capacity stabilized at 8.71 mmol·g−1, while mechanical strength was maintained at 8.92 MPa. Through characterization, it was revealed that the pore structure generated by the pyrolysis of the granulation promoters notably increased the specific surface area, leading to high CO2 capture capacity. Meanwhile, the strengthened mechanical strength of the alkaline metal salt-promoted MgO sorbent pellets was primarily due to the in situ formation of a γ-AlOOH sol-gel cluster skeleton. Thus, this study provides an effective technological pathway to enhance the performance of the alkaline metal salt-promoted MgO sorbent pellets for industrial applications.
期刊介绍:
Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.