{"title":"等离子体催化Ni/Hβ沸石上的聚乙烯裂解为轻烃燃料和氢气,无需外部加热","authors":"Jianhui Han, Tianqi Yun, Chengxin Hou, Bingbing Chen, Tianhao Shi, Yanan Diao, Chuan Shi","doi":"10.1007/s11705-025-2583-9","DOIUrl":null,"url":null,"abstract":"<div><p>The rapid accumulation of plastic waste poses severe environmental challenges. Cold plasma-driven degradation offers a promising route to convert plastic waste into high-value chemicals. In this study, a single-stage plasma reactor coupling cold plasma (dielectric barrier discharge) with H<i>β</i> zeolites was developed for polyethylene degradation under relatively mild conditions, without external thermal input or participation of noble metals. The effects of zeolite pore structure and acidity toward product distribution were investigated, revealing that H<i>β</i>-25 exhibited the highest C<sub>1</sub>–C<sub>6</sub> yield (76 wt %) and a space-time yield of 103.8 mmol·g<sub>cat</sub><sup>−1</sup>·h<sup>−1</sup> compared to other zeolite catalysts during the plasma-catalytic process. Meanwhile, it was revealed that efficient pre-cracking initiated by plasma activation and the optimal structural compatibility between H<i>β</i>-zeolite pore channels and primary cracking products were the key factors enabling the selective conversion of polyethylene into C<sub>1</sub>–C<sub>6</sub> hydrocarbons. Additionally, metal incorporation significantly enhanced C–H bond cleavage compared to H<i>β</i>-25 support. Especially, 10Ni/H<i>β</i>-25 exhibited the highest hydrogen yield (7.87 mmol·g<sub>plastic</sub><sup>−1</sup>) under plasma-assisted mode, markedly surpassing its yield under thermal-cracking conditions, demonstrating the significant potential of plasma-catalytic degradation for hydrogen production from polyethylene.\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"19 8","pages":""},"PeriodicalIF":4.5000,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Plasma-catalytic cracking of polyethylene over Ni/Hβ zeolites to light hydrocarbon fuels and hydrogen without external heating\",\"authors\":\"Jianhui Han, Tianqi Yun, Chengxin Hou, Bingbing Chen, Tianhao Shi, Yanan Diao, Chuan Shi\",\"doi\":\"10.1007/s11705-025-2583-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The rapid accumulation of plastic waste poses severe environmental challenges. Cold plasma-driven degradation offers a promising route to convert plastic waste into high-value chemicals. In this study, a single-stage plasma reactor coupling cold plasma (dielectric barrier discharge) with H<i>β</i> zeolites was developed for polyethylene degradation under relatively mild conditions, without external thermal input or participation of noble metals. The effects of zeolite pore structure and acidity toward product distribution were investigated, revealing that H<i>β</i>-25 exhibited the highest C<sub>1</sub>–C<sub>6</sub> yield (76 wt %) and a space-time yield of 103.8 mmol·g<sub>cat</sub><sup>−1</sup>·h<sup>−1</sup> compared to other zeolite catalysts during the plasma-catalytic process. Meanwhile, it was revealed that efficient pre-cracking initiated by plasma activation and the optimal structural compatibility between H<i>β</i>-zeolite pore channels and primary cracking products were the key factors enabling the selective conversion of polyethylene into C<sub>1</sub>–C<sub>6</sub> hydrocarbons. Additionally, metal incorporation significantly enhanced C–H bond cleavage compared to H<i>β</i>-25 support. Especially, 10Ni/H<i>β</i>-25 exhibited the highest hydrogen yield (7.87 mmol·g<sub>plastic</sub><sup>−1</sup>) under plasma-assisted mode, markedly surpassing its yield under thermal-cracking conditions, demonstrating the significant potential of plasma-catalytic degradation for hydrogen production from polyethylene.\\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":571,\"journal\":{\"name\":\"Frontiers of Chemical Science and Engineering\",\"volume\":\"19 8\",\"pages\":\"\"},\"PeriodicalIF\":4.5000,\"publicationDate\":\"2025-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Frontiers of Chemical Science and Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11705-025-2583-9\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers of Chemical Science and Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11705-025-2583-9","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Plasma-catalytic cracking of polyethylene over Ni/Hβ zeolites to light hydrocarbon fuels and hydrogen without external heating
The rapid accumulation of plastic waste poses severe environmental challenges. Cold plasma-driven degradation offers a promising route to convert plastic waste into high-value chemicals. In this study, a single-stage plasma reactor coupling cold plasma (dielectric barrier discharge) with Hβ zeolites was developed for polyethylene degradation under relatively mild conditions, without external thermal input or participation of noble metals. The effects of zeolite pore structure and acidity toward product distribution were investigated, revealing that Hβ-25 exhibited the highest C1–C6 yield (76 wt %) and a space-time yield of 103.8 mmol·gcat−1·h−1 compared to other zeolite catalysts during the plasma-catalytic process. Meanwhile, it was revealed that efficient pre-cracking initiated by plasma activation and the optimal structural compatibility between Hβ-zeolite pore channels and primary cracking products were the key factors enabling the selective conversion of polyethylene into C1–C6 hydrocarbons. Additionally, metal incorporation significantly enhanced C–H bond cleavage compared to Hβ-25 support. Especially, 10Ni/Hβ-25 exhibited the highest hydrogen yield (7.87 mmol·gplastic−1) under plasma-assisted mode, markedly surpassing its yield under thermal-cracking conditions, demonstrating the significant potential of plasma-catalytic degradation for hydrogen production from polyethylene.
期刊介绍:
Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.