干混凝土废浆中无水水泥的高回收率,可作为低二氧化碳混凝土的补充胶凝材料

IF 6.5 Q2 ENGINEERING, ENVIRONMENTAL
Daniel O.F. Silva , Valdir M. Pereira , Antônio C.V. Coelho , Sérgio C. Angulo
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引用次数: 0

摘要

混凝土浆料废料(CSW)是混凝土回收和搅拌车洗涤过程中产生的副产品,约占混凝土总产量的3-5%。虽然已经开发了各种回收CSW的策略,但大规模回收其无水水泥部分,如本研究中所实施的,以前还没有报道。此外,之前的研究几乎都集中在使用低反应性的CSW作为补充胶凝材料(SCM)。在本研究中,在CSW返回预拌混凝土厂(RMCP)后,对其进行过滤和快速干燥处理。考察了回收时间和混凝土废料种类对无水水泥保存率的影响。回收的材料随后被用于部分替代水泥膏体配方中的波特兰水泥。采用x射线荧光、HCl浸出、热重、等温量热、定量x射线衍射等分析方法对样品进行了表征。结果表明,由于过滤和快速干燥过程的效率,CSW中的无水水泥含量显著增加,按质量计约为30%。此外,水浸时间对无水水泥保有量无显著影响。选择三种CSW样品并将其掺入水泥浆中,取代35% -75%(质量)的波特兰水泥。所得到的膏体的机械强度值与100%波特兰水泥制成的参考膏体相当,或在统计上等效。回收方法有潜力发展零废物预拌混凝土工厂,本研究中提出的低排放混凝土配方可以减少高达55%的特定二氧化碳排放量。这种方法可以在预拌料操作中减少大约15%的波特兰水泥消耗(按质量计算),为混凝土行业的可持续性做出重大贡献。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
High recovery of anhydrous cement in dried concrete slurry waste for use as supplementary cementitious material in low-CO2 concretes
Concrete slurry waste (CSW) is a by-product generated from returned concrete and the mixer truck washing process, accounting for approximately 3–5% of total concrete production. Although various strategies for recycling CSW have been developed, large-scale recovery of its anhydrous cement fraction, such implemented in the present study, has not been previously reported. Moreover, prior studies have focused almost exclusively on the use of low-reactivity CSW as a supplementary cementitious material (SCM). In this study, a filtering and rapid drying procedure was applied to CSW upon its return to the ready-mixed concrete plant (RMCP). The influence of the recovery time and type of concrete waste on the preservation of the anhydrous cement fraction was evaluated. The recovered material was subsequently used to partially replace Portland cement in cementitious paste formulations. The samples were characterized using analytical methods, such X-ray fluorescence, HCl leaching assay, thermogravimetric analysis, isothermal calorimetry, and quantitative X-ray diffraction (QXRD). The results demonstrated that the anhydrous cement content in CSW was significant, approximately 30% by mass, due to the efficiency of the filtering and rapid drying process. Furthermore, the time exposure to water had no notable effect on the preserved anhydrous cement fraction. Three CSW samples were selected and incorporated into cement pastes, replacing 35 %–75% (by mass) of Portland cement. The resulting pastes exhibited mechanical strength values comparable to, or statistically equivalent to, those of the reference paste made with 100 % Portland cement. The recovery methodology has potential for the development of zero-waste ready-mix concrete plants, and the low emission concrete formulation proposed in this study enabled a reduction of up to 55% in specific CO2 emissions. This approach could reduce Portland cement consumption by approximately 15% (by mass) in ready-mix operations, contributing significantly to sustainability in the concrete industry.
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来源期刊
Cleaner Engineering and Technology
Cleaner Engineering and Technology Engineering-Engineering (miscellaneous)
CiteScore
9.80
自引率
0.00%
发文量
218
审稿时长
21 weeks
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