Xiaolei Han , Binbin Liu , Shuyi Xie , Cong Zhang , Li Huang , Wei Liu , Huaping Xiong , Feng Ye
{"title":"揭示了硅化物强化(TiZrHfNb)100- x6 (x = 0、1、5、7、10和15)难熔高熵合金的显微组织演变和力学性能","authors":"Xiaolei Han , Binbin Liu , Shuyi Xie , Cong Zhang , Li Huang , Wei Liu , Huaping Xiong , Feng Ye","doi":"10.1016/j.matdes.2025.114825","DOIUrl":null,"url":null,"abstract":"<div><div>The ductile TiZrHfNb refractory high-entropy alloy is selected to form silicide-strengthened (TiZrHfNb)<sub>100-x</sub>Si<sub>x</sub> (x = 0, 1, 5, 7, 10 and 15, in at. %) alloys, and the influence of Si content on the microstructure and mechanical properties was systematically investigated. The solidification microstructure and the type of silicide show strong dependence on Si content from 1 % to 15 %, with the former changing from hypoeutectic to hypereutectic structure, and the latter evolving from M<sub>3</sub>Si-type to tetragonal-M<sub>5</sub>Si<sub>3</sub>-type silicide, and finally to the co-existence of both tetragonal- and hexagonal- M<sub>5</sub>Si<sub>3</sub>-type silicide. The formation of silicide phase enhances the strength both at the ambient and elevated temperatures, and a significant improvement of peak compressive strength from 221.3 MPa to 511.59 MPa at 800℃ was obtained after alloying 15 % Si to the prototype TiZrHfNb alloy. It was found that heterodeformation-induced strengthening, resulting from dislocation pile-ups at phase boundaries, was responsible for the enhancement in the strength. During hot deformation, the flow stress begins to decrease after reaching the peak value due to the presence of the dynamic recovery and dynamic recrystallization, which becomes more pronounced at higher Si content.</div></div>","PeriodicalId":383,"journal":{"name":"Materials & Design","volume":"259 ","pages":"Article 114825"},"PeriodicalIF":7.9000,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Unveiling microstructure evolution and mechanical properties of silicide-strengthened (TiZrHfNb)100-xSix (x = 0, 1, 5, 7, 10 and 15) refractory high-entropy alloys\",\"authors\":\"Xiaolei Han , Binbin Liu , Shuyi Xie , Cong Zhang , Li Huang , Wei Liu , Huaping Xiong , Feng Ye\",\"doi\":\"10.1016/j.matdes.2025.114825\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The ductile TiZrHfNb refractory high-entropy alloy is selected to form silicide-strengthened (TiZrHfNb)<sub>100-x</sub>Si<sub>x</sub> (x = 0, 1, 5, 7, 10 and 15, in at. %) alloys, and the influence of Si content on the microstructure and mechanical properties was systematically investigated. The solidification microstructure and the type of silicide show strong dependence on Si content from 1 % to 15 %, with the former changing from hypoeutectic to hypereutectic structure, and the latter evolving from M<sub>3</sub>Si-type to tetragonal-M<sub>5</sub>Si<sub>3</sub>-type silicide, and finally to the co-existence of both tetragonal- and hexagonal- M<sub>5</sub>Si<sub>3</sub>-type silicide. The formation of silicide phase enhances the strength both at the ambient and elevated temperatures, and a significant improvement of peak compressive strength from 221.3 MPa to 511.59 MPa at 800℃ was obtained after alloying 15 % Si to the prototype TiZrHfNb alloy. It was found that heterodeformation-induced strengthening, resulting from dislocation pile-ups at phase boundaries, was responsible for the enhancement in the strength. During hot deformation, the flow stress begins to decrease after reaching the peak value due to the presence of the dynamic recovery and dynamic recrystallization, which becomes more pronounced at higher Si content.</div></div>\",\"PeriodicalId\":383,\"journal\":{\"name\":\"Materials & Design\",\"volume\":\"259 \",\"pages\":\"Article 114825\"},\"PeriodicalIF\":7.9000,\"publicationDate\":\"2025-09-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials & Design\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0264127525012456\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials & Design","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0264127525012456","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Unveiling microstructure evolution and mechanical properties of silicide-strengthened (TiZrHfNb)100-xSix (x = 0, 1, 5, 7, 10 and 15) refractory high-entropy alloys
The ductile TiZrHfNb refractory high-entropy alloy is selected to form silicide-strengthened (TiZrHfNb)100-xSix (x = 0, 1, 5, 7, 10 and 15, in at. %) alloys, and the influence of Si content on the microstructure and mechanical properties was systematically investigated. The solidification microstructure and the type of silicide show strong dependence on Si content from 1 % to 15 %, with the former changing from hypoeutectic to hypereutectic structure, and the latter evolving from M3Si-type to tetragonal-M5Si3-type silicide, and finally to the co-existence of both tetragonal- and hexagonal- M5Si3-type silicide. The formation of silicide phase enhances the strength both at the ambient and elevated temperatures, and a significant improvement of peak compressive strength from 221.3 MPa to 511.59 MPa at 800℃ was obtained after alloying 15 % Si to the prototype TiZrHfNb alloy. It was found that heterodeformation-induced strengthening, resulting from dislocation pile-ups at phase boundaries, was responsible for the enhancement in the strength. During hot deformation, the flow stress begins to decrease after reaching the peak value due to the presence of the dynamic recovery and dynamic recrystallization, which becomes more pronounced at higher Si content.
期刊介绍:
Materials and Design is a multi-disciplinary journal that publishes original research reports, review articles, and express communications. The journal focuses on studying the structure and properties of inorganic and organic materials, advancements in synthesis, processing, characterization, and testing, the design of materials and engineering systems, and their applications in technology. It aims to bring together various aspects of materials science, engineering, physics, and chemistry.
The journal explores themes ranging from materials to design and aims to reveal the connections between natural and artificial materials, as well as experiment and modeling. Manuscripts submitted to Materials and Design should contain elements of discovery and surprise, as they often contribute new insights into the architecture and function of matter.