{"title":"聚氨酯-碳纳米管复合泡沫的亚太赫兹吸收屏蔽性能","authors":"Ahmad Mamoun Khamis , Laetitia Urbanczyk , Christophe Detrembleur , Isabelle Huynen","doi":"10.1016/j.materresbull.2025.113793","DOIUrl":null,"url":null,"abstract":"<div><div>This study presents a novel investigation of the impact of multiwalled carbon nanotube (CNT) on the microstructure and electromagnetic shielding properties of polyurethane (PU) foams across an exceptional ultra-wideband frequency range, from 5.85 GHz to 330 GHz. The microstructure results show that the CNT formed an interconnected and well-distributed network on the PU surface. In addition, increasing CNT content from 1 wt.% to 11.2 wt.% significantly enhanced the total shielding effectiveness (SE<sub>T</sub>) by approximately four times over the whole frequency range. The absorption is identified as the main mechanism contributing to the SE<sub>T</sub> performance of our 2.4 mm-thick foamed composite samples, representing >98 % of the SE<sub>T</sub> above 40 GHz and up to 330 GHz. Hence, the corresponding absorption level achieved in this range is 13 – 45 dB. Our samples exhibit significant potential for electromagnetic interference shielding applications since they meet the standard commercial requirements.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"194 ","pages":"Article 113793"},"PeriodicalIF":5.7000,"publicationDate":"2025-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sub-terahertz absorption shielding performances of polyurethane - Carbon nanotubes composite foams\",\"authors\":\"Ahmad Mamoun Khamis , Laetitia Urbanczyk , Christophe Detrembleur , Isabelle Huynen\",\"doi\":\"10.1016/j.materresbull.2025.113793\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study presents a novel investigation of the impact of multiwalled carbon nanotube (CNT) on the microstructure and electromagnetic shielding properties of polyurethane (PU) foams across an exceptional ultra-wideband frequency range, from 5.85 GHz to 330 GHz. The microstructure results show that the CNT formed an interconnected and well-distributed network on the PU surface. In addition, increasing CNT content from 1 wt.% to 11.2 wt.% significantly enhanced the total shielding effectiveness (SE<sub>T</sub>) by approximately four times over the whole frequency range. The absorption is identified as the main mechanism contributing to the SE<sub>T</sub> performance of our 2.4 mm-thick foamed composite samples, representing >98 % of the SE<sub>T</sub> above 40 GHz and up to 330 GHz. Hence, the corresponding absorption level achieved in this range is 13 – 45 dB. Our samples exhibit significant potential for electromagnetic interference shielding applications since they meet the standard commercial requirements.</div></div>\",\"PeriodicalId\":18265,\"journal\":{\"name\":\"Materials Research Bulletin\",\"volume\":\"194 \",\"pages\":\"Article 113793\"},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2025-09-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Research Bulletin\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0025540825005008\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Research Bulletin","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025540825005008","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
This study presents a novel investigation of the impact of multiwalled carbon nanotube (CNT) on the microstructure and electromagnetic shielding properties of polyurethane (PU) foams across an exceptional ultra-wideband frequency range, from 5.85 GHz to 330 GHz. The microstructure results show that the CNT formed an interconnected and well-distributed network on the PU surface. In addition, increasing CNT content from 1 wt.% to 11.2 wt.% significantly enhanced the total shielding effectiveness (SET) by approximately four times over the whole frequency range. The absorption is identified as the main mechanism contributing to the SET performance of our 2.4 mm-thick foamed composite samples, representing >98 % of the SET above 40 GHz and up to 330 GHz. Hence, the corresponding absorption level achieved in this range is 13 – 45 dB. Our samples exhibit significant potential for electromagnetic interference shielding applications since they meet the standard commercial requirements.
期刊介绍:
Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.