用于沙丁胺醇分子敏感检测的锌基配位超分子传感器

IF 3.7 2区 化学 Q2 CHEMISTRY, APPLIED
Ling Yue, Jingjing Qiao, Yefang Yang, Shaowen Qie, Zhilin Mu, Yongyang Chen, Yuejiao Jia, Ming Hu
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引用次数: 0

摘要

沙丁胺醇是一种被滥用于兴奋剂和瘦肉粉中的禁用物质,对人体健康构成潜在威胁。本文以2-(2′-吡啶基)苯并咪唑-5-羧酸(Hpbca)配体与硫酸锌在溶剂热条件下自组装制备了发光锌基配位超分子传感器,即[Zn2(pbca)2(SO4)(H2O)3](1),可作为检测SAL的高效荧光探针。单晶x射线衍射分析表明,配合物1具有独特的双核构建单元,它们通过π···π堆叠和氢键的相互作用相互连接,形成三维超分子框架。配合物1具有高灵敏度(检测限:0.357 ppm)、良好的抗干扰性和快速的响应时间。通过综合实验和DFT计算,系统研究了配合物1对SAL的荧光感应机理。在实际应用中,我们将复合物1加入到聚合物材料中,开发了便携式低成本测试条,在365 nm的紫外线照射下,通过明显的颜色变化实现了视觉SAL检测。这些复合膜在裸眼识别SAL方面表现出可靠的性能,为反兴奋剂和食品安全领域的现场监测提供了良好的可行性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A Zinc-Based Coordination Supramolecule Sensor for Sensitive Detection of Salbutamol Molecule

A Zinc-Based Coordination Supramolecule Sensor for Sensitive Detection of Salbutamol Molecule

As a banned substance misused in doping drugs and lean meat powders, salbutamol (SAL) poses a potential threat to human health. Here, a luminescence zinc-based coordination supramolecule sensor was constructed from 2-(2′-pyridyl)benzimidazole-5-carboxylic acid (Hpbca) ligand and zinc sulfate in the self-assembly process under solvothermal conditions, namely, [Zn2(pbca)2(SO4)(H2O)3] (1), which could function as an efficient fluorescence probe for the detection of SAL. The single-crystal X-ray diffraction analysis reveals that complex 1 possesses distinctive binuclear building units, which are interlinked to form a three-dimensional supramolecule framework through the interactions of π···π stacking and hydrogen bonding. Complex 1 demonstrated exceptional performances with a high sensitivity (the limit of detection: 0.357 ppm), excellent anti-interference, and rapid response time. The fluorescence sensing mechanism of complex 1 toward SAL was systematically investigated through comprehensive experiments and DFT calculations. For practical implementations, we developed portable low-cost test strips by incorporating complex 1 into polymer materials, which enabled visual SAL detection through distinct color changes under the UV irradiation of 365 nm. These composite films exhibited reliable performance in recognizing SAL with the naked eye, offering promising feasibility for on-site monitoring in the fields of anti-doping and food safety.

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来源期刊
Applied Organometallic Chemistry
Applied Organometallic Chemistry 化学-无机化学与核化学
CiteScore
7.80
自引率
10.30%
发文量
408
审稿时长
2.2 months
期刊介绍: All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.
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