基于Li2CoMn3O8固溶体复合合成正极材料新方法的发展

IF 1.5 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
R. I. Korneykov, V. V. Efremov, S. V. Aksenova, K. A. Kesarev, O. I. Akhmetov, O. B. Shcherbina, I. R. Elizarova, I. G. Tananaev, O. O. Shichalin
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引用次数: 0

摘要

采用复合方法合成了基于Li2CoMn3O8固溶体的正极材料,并对其性能进行了研究。研究发现,Li2CoMn3O8具有较高的电化学性能,是锂离子电池极具前景的正极材料,可以替代LiCoO2。利用x射线衍射分析和光谱分析,鉴定了所得相,并确定了其化学成分。用电子显微镜和brunauer - emmet - teller方法对其结构和形貌进行了研究。提出了一种制备Li2CoMn3O8的工艺方案,该方案可确保形成具有高比表面积和改善电化学特性的纳米级样品。讨论了合成样品的电化学性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Development of a New Combined Approach to the Synthesis of a Cathode Material Based on the Li2CoMn3O8 Solid Solution

Development of a New Combined Approach to the Synthesis of a Cathode Material Based on the Li2CoMn3O8 Solid Solution

Cathode materials based on Li2CoMn3O8 solid solutions have been synthesized by a combined method and their characteristics have been studied. It has been found that Li2CoMn3O8 has high electrochemical properties, which makes it a promising cathode material for lithium-ion batteries, an alternative to LiCoO2. Using X-ray diffraction analysis and spectrometry, the resulting phases have been identified, and their chemical composition has been determined. The structure and morphology have been studied by electron microscopy and Brunauer–Emmett–Teller methods. A technological scheme for fabricating Li2CoMn3O8 has been proposed, which ensures the formation of nanosized samples with a high specific surface area and improved electrochemical characteristics. The electrochemical properties of the synthesized samples are discussed.

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来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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