R. I. Korneykov, V. V. Efremov, S. V. Aksenova, K. A. Kesarev, O. I. Akhmetov, O. B. Shcherbina, I. R. Elizarova, I. G. Tananaev, O. O. Shichalin
{"title":"基于Li2CoMn3O8固溶体复合合成正极材料新方法的发展","authors":"R. I. Korneykov, V. V. Efremov, S. V. Aksenova, K. A. Kesarev, O. I. Akhmetov, O. B. Shcherbina, I. R. Elizarova, I. G. Tananaev, O. O. Shichalin","doi":"10.1134/S0036023625600236","DOIUrl":null,"url":null,"abstract":"<p>Cathode materials based on Li<sub>2</sub>CoMn<sub>3</sub>O<sub>8</sub> solid solutions have been synthesized by a combined method and their characteristics have been studied. It has been found that Li<sub>2</sub>CoMn<sub>3</sub>O<sub>8</sub> has high electrochemical properties, which makes it a promising cathode material for lithium-ion batteries, an alternative to LiCoO<sub>2</sub>. Using X-ray diffraction analysis and spectrometry, the resulting phases have been identified, and their chemical composition has been determined. The structure and morphology have been studied by electron microscopy and Brunauer–Emmett–Teller methods. A technological scheme for fabricating Li<sub>2</sub>CoMn<sub>3</sub>O<sub>8</sub> has been proposed, which ensures the formation of nanosized samples with a high specific surface area and improved electrochemical characteristics. The electrochemical properties of the synthesized samples are discussed.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"70 and Development Prospects","pages":"337 - 346"},"PeriodicalIF":1.5000,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development of a New Combined Approach to the Synthesis of a Cathode Material Based on the Li2CoMn3O8 Solid Solution\",\"authors\":\"R. I. Korneykov, V. V. Efremov, S. V. Aksenova, K. A. Kesarev, O. I. Akhmetov, O. B. Shcherbina, I. R. Elizarova, I. G. Tananaev, O. O. Shichalin\",\"doi\":\"10.1134/S0036023625600236\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Cathode materials based on Li<sub>2</sub>CoMn<sub>3</sub>O<sub>8</sub> solid solutions have been synthesized by a combined method and their characteristics have been studied. It has been found that Li<sub>2</sub>CoMn<sub>3</sub>O<sub>8</sub> has high electrochemical properties, which makes it a promising cathode material for lithium-ion batteries, an alternative to LiCoO<sub>2</sub>. Using X-ray diffraction analysis and spectrometry, the resulting phases have been identified, and their chemical composition has been determined. The structure and morphology have been studied by electron microscopy and Brunauer–Emmett–Teller methods. A technological scheme for fabricating Li<sub>2</sub>CoMn<sub>3</sub>O<sub>8</sub> has been proposed, which ensures the formation of nanosized samples with a high specific surface area and improved electrochemical characteristics. The electrochemical properties of the synthesized samples are discussed.</p>\",\"PeriodicalId\":762,\"journal\":{\"name\":\"Russian Journal of Inorganic Chemistry\",\"volume\":\"70 and Development Prospects\",\"pages\":\"337 - 346\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2025-06-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036023625600236\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036023625600236","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Development of a New Combined Approach to the Synthesis of a Cathode Material Based on the Li2CoMn3O8 Solid Solution
Cathode materials based on Li2CoMn3O8 solid solutions have been synthesized by a combined method and their characteristics have been studied. It has been found that Li2CoMn3O8 has high electrochemical properties, which makes it a promising cathode material for lithium-ion batteries, an alternative to LiCoO2. Using X-ray diffraction analysis and spectrometry, the resulting phases have been identified, and their chemical composition has been determined. The structure and morphology have been studied by electron microscopy and Brunauer–Emmett–Teller methods. A technological scheme for fabricating Li2CoMn3O8 has been proposed, which ensures the formation of nanosized samples with a high specific surface area and improved electrochemical characteristics. The electrochemical properties of the synthesized samples are discussed.
期刊介绍:
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.