成分配比对聚酰胺6与热塑性聚酰胺弹性体自卷曲双组分纤维性能的影响

IF 2.3 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES
Man Zhao, Qian Yang, Mengdie Liao, Ming Weng, Xiuhua Wang
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引用次数: 0

摘要

自卷曲双组分纤维被广泛应用于纺织品中,以改善纺织品的弹性和蓬松性。迄今为止,虽然已经开发出许多基于聚酯的自卷曲双组分纤维,但基于聚酰胺(PA)的自卷曲双组分纤维却很少报道。采用熔融纺丝法制备了PA/热塑性PA弹性体(TPAE)比分别为35/65、40/60、45/55和50/50的自卷曲双组分纤维,研究了组分比对纤维性能的影响。PA/TPAE双组分纤维的横截面从偏心皮芯到并排,其中PA/TPAE界面由曲线变为直线。结果表明,PA含量的增加有助于提高材料的结晶度、取向、拉伸强度和热收缩强度,TPAE含量的增加有助于提高材料的热收缩率和弹性回复率。PA/TPAE双组分纤维具有中等的力学性能和优异的弹性回复率,可以满足纺织加工的要求。此外,PA/TPAE纤维的卷曲行为与聚酯基纤维的卷曲行为以及现有理论的预测有所偏差。本文为自卷曲纤维的生产提供了一条新途径,该方法适用于大规模生产。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Composition Ratio on Properties of Self-Crimping Bicomponent Fibers Composed of Polyamide 6 and Thermoplastic Polyamide Elastomer

Self-crimping bicomponent fibers have been widely used in textile products to improve properties, such as elasticity and fluffiness. So far, although many polyester-based self-crimping bicomponent fibers have been developed, polyamide (PA)-based ones are rarely reported. In this paper, self-crimping bicomponent fibers with PA/thermoplastic PA elastomer (TPAE) ratios of 35/65, 40/60, 45/55, and 50/50 were fabricated via melt spinning, and the effect of composition ratio on the properties of the fibers was investigated. The cross-sections of PA/TPAE bicomponent fibers varied from eccentric sheath-core to side-by-side, therein PA/TPAE interface changed from a curve to a straight line. The results showed that the increase in PA content contributed to the improvements in crystallinity, orientation, tensile tenacity, and thermal shrinkage strength, while that in TPAE content to the improvements in thermal shrinkage rate and elastic recovery rate. PA/TPAE bicomponent fibers had moderate mechanical properties and excellent elastic recovery, and hence can meet the requirements for textile processing. It is also noticed that the crimp behavior of PA/TPAE fibers was deviated from that of polyester-based side-by-side fibers as well as the predictions from current theories. This paper provides a new way to producing self-crimping fibers, the proposed fabrication method is applicable for large-scale production.

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来源期刊
Fibers and Polymers
Fibers and Polymers 工程技术-材料科学:纺织
CiteScore
3.90
自引率
8.00%
发文量
267
审稿时长
3.9 months
期刊介绍: -Chemistry of Fiber Materials, Polymer Reactions and Synthesis- Physical Properties of Fibers, Polymer Blends and Composites- Fiber Spinning and Textile Processing, Polymer Physics, Morphology- Colorants and Dyeing, Polymer Analysis and Characterization- Chemical Aftertreatment of Textiles, Polymer Processing and Rheology- Textile and Apparel Science, Functional Polymers
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