Bingying Li, Mengen Zhong, Songlin Zuo, Debin Wang
{"title":"木质素衍生的富硫活性炭中k2s介导的分级孔工程用于增强元素汞捕获","authors":"Bingying Li, Mengen Zhong, Songlin Zuo, Debin Wang","doi":"10.1007/s10853-025-11494-1","DOIUrl":null,"url":null,"abstract":"<div><p>Sulfur-functionalized porous carbons have garnered significant attention for multifunctional applications ranging from energy storage to environmental remediation. This study introduces an innovative single-step K<sub>2</sub>S activation strategy for converting renewable lignin into high-surface-area sulfur-enriched porous carbons with hierarchical porosity. The results showed that the activation parameters of K<sub>2</sub>S/lignin mass ratios (0.5:1 to 3:1) and thermal activation temperatures (600–850 °C) critically govern the resultant pore structure, sulfur content (5.0–12.5 wt%), and sulfur speciation distribution. The characterization reveals three dominant sulfur configurations: elemental (S<sup>0</sup>), thiophenic (C–S–C), and sulfonic (C–S=O) moieties, with their relative distribution being thermally modulable. Post-synthesis treatments through methanol extraction and thermal annealing (800 °C/N<sub>2</sub>) were found to effectively eliminate pore-blocking S<sup>0</sup> species while enhancing textural properties, achieving exceptional Brunauer–Emmett–Teller surface areas (2500 m<sup>2</sup> g<sup>−1</sup>) and total pore volumes (2.4 cm<sup>3</sup> g<sup>−1</sup>) at optimal conditions. This pore evolution suggests a dual mechanism where elemental sulfur acts as both a porogen and reactive intermediate during K<sub>2</sub>S activation. The optimized sulfur-containing porous carbons exhibited superior elemental mercury adsorption capacity (44 mg g<sup>−1</sup>), outperforming conventional sulfur-impregnated carbons. This work establishes K<sub>2</sub>S activation as a sustainable paradigm for fabricating hierarchically sulfur-containing porous carbons, combining renewable feedstocks with tailorable surface chemistry for advanced environmental applications.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"60 38","pages":"17492 - 17511"},"PeriodicalIF":3.9000,"publicationDate":"2025-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"K2S-mediated hierarchical pore engineering in lignin-derived sulfur-enriched activated carbons for enhanced elemental mercury capture\",\"authors\":\"Bingying Li, Mengen Zhong, Songlin Zuo, Debin Wang\",\"doi\":\"10.1007/s10853-025-11494-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Sulfur-functionalized porous carbons have garnered significant attention for multifunctional applications ranging from energy storage to environmental remediation. This study introduces an innovative single-step K<sub>2</sub>S activation strategy for converting renewable lignin into high-surface-area sulfur-enriched porous carbons with hierarchical porosity. The results showed that the activation parameters of K<sub>2</sub>S/lignin mass ratios (0.5:1 to 3:1) and thermal activation temperatures (600–850 °C) critically govern the resultant pore structure, sulfur content (5.0–12.5 wt%), and sulfur speciation distribution. The characterization reveals three dominant sulfur configurations: elemental (S<sup>0</sup>), thiophenic (C–S–C), and sulfonic (C–S=O) moieties, with their relative distribution being thermally modulable. Post-synthesis treatments through methanol extraction and thermal annealing (800 °C/N<sub>2</sub>) were found to effectively eliminate pore-blocking S<sup>0</sup> species while enhancing textural properties, achieving exceptional Brunauer–Emmett–Teller surface areas (2500 m<sup>2</sup> g<sup>−1</sup>) and total pore volumes (2.4 cm<sup>3</sup> g<sup>−1</sup>) at optimal conditions. This pore evolution suggests a dual mechanism where elemental sulfur acts as both a porogen and reactive intermediate during K<sub>2</sub>S activation. The optimized sulfur-containing porous carbons exhibited superior elemental mercury adsorption capacity (44 mg g<sup>−1</sup>), outperforming conventional sulfur-impregnated carbons. This work establishes K<sub>2</sub>S activation as a sustainable paradigm for fabricating hierarchically sulfur-containing porous carbons, combining renewable feedstocks with tailorable surface chemistry for advanced environmental applications.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":645,\"journal\":{\"name\":\"Journal of Materials Science\",\"volume\":\"60 38\",\"pages\":\"17492 - 17511\"},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2025-09-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10853-025-11494-1\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Science","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10853-025-11494-1","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
K2S-mediated hierarchical pore engineering in lignin-derived sulfur-enriched activated carbons for enhanced elemental mercury capture
Sulfur-functionalized porous carbons have garnered significant attention for multifunctional applications ranging from energy storage to environmental remediation. This study introduces an innovative single-step K2S activation strategy for converting renewable lignin into high-surface-area sulfur-enriched porous carbons with hierarchical porosity. The results showed that the activation parameters of K2S/lignin mass ratios (0.5:1 to 3:1) and thermal activation temperatures (600–850 °C) critically govern the resultant pore structure, sulfur content (5.0–12.5 wt%), and sulfur speciation distribution. The characterization reveals three dominant sulfur configurations: elemental (S0), thiophenic (C–S–C), and sulfonic (C–S=O) moieties, with their relative distribution being thermally modulable. Post-synthesis treatments through methanol extraction and thermal annealing (800 °C/N2) were found to effectively eliminate pore-blocking S0 species while enhancing textural properties, achieving exceptional Brunauer–Emmett–Teller surface areas (2500 m2 g−1) and total pore volumes (2.4 cm3 g−1) at optimal conditions. This pore evolution suggests a dual mechanism where elemental sulfur acts as both a porogen and reactive intermediate during K2S activation. The optimized sulfur-containing porous carbons exhibited superior elemental mercury adsorption capacity (44 mg g−1), outperforming conventional sulfur-impregnated carbons. This work establishes K2S activation as a sustainable paradigm for fabricating hierarchically sulfur-containing porous carbons, combining renewable feedstocks with tailorable surface chemistry for advanced environmental applications.
期刊介绍:
The Journal of Materials Science publishes reviews, full-length papers, and short Communications recording original research results on, or techniques for studying the relationship between structure, properties, and uses of materials. The subjects are seen from international and interdisciplinary perspectives covering areas including metals, ceramics, glasses, polymers, electrical materials, composite materials, fibers, nanostructured materials, nanocomposites, and biological and biomedical materials. The Journal of Materials Science is now firmly established as the leading source of primary communication for scientists investigating the structure and properties of all engineering materials.