Cu3P/Zn0.8Cd0.2S/g-C3N4三元纳米复合材料通过双z方案光催化结构高效可见光降解亚甲基蓝

IF 2.6 4区 化学 Q3 CHEMISTRY, PHYSICAL
Ionics Pub Date : 2025-06-16 DOI:10.1007/s11581-025-06464-1
Mohamad Amin Ziveh, Fatemeh Sousani, Sayed Khatiboleslam Sadrnezhaad, Mukul Sethi
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引用次数: 0

摘要

本研究旨在通过构建新型Cu3P/Zn0.8Cd0.2S/g-C3N4三元纳米复合材料,提高石墨氮化碳(g-C3N4)对可见光驱动污染物降解的光催化效率。采用水热法合成了Cu3P/Zn0.8Cd0.2S/g-C3N4。采用XRD、FTIR、XPS、BET、FE-SEM、EDS、TEM、UV-Vis DRS、PL、EIS、光电流响应、Mott-Schottky和UV-Vis光谱对复合材料的结构特征、形貌和光催化性能进行了评价。在LED灯(100 W, 400-700 nm)照射下,光催化降解亚甲基蓝水溶液3 h。5%-Cu3P/Zn0.8Cd0.2S/g-C3N4复合材料表现出最高的光催化效率,在180 min内对MB的降解率为95.64%,在30 min内降解率为72.09%,表观速率常数为0.0131 min−1,大大优于单个组分(g-C3N4在180 min内降解58.55%,Zn0.8Cd0.2S降解58.63%,Cu3P降解70.15%)。Cu3P/Zn0.8Cd0.2S/g-C3N4光催化性能的提高主要是由于在g-C3N4、Zn0.8Cd0.2S和Cu3P之间构建了双Z-scheme异质结,促进了光激发电荷转运体的分离和运动。本研究证明了Cu3P/Zn0.8Cd0.2S/g-C3N4异质结作为一种不含贵金属且具有成本效益的废水处理光催化剂的潜力,表明其在水分解、二氧化碳还原和抗菌活性等其他用途上的适用性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Cu3P/Zn0.8Cd0.2S/g-C3N4 ternary nanocomposite for efficient visible-light-driven degradation of methylene blue through a dual Z-scheme photocatalytic configuration

This research intends to improve the photocatalytic efficiency of graphitic carbon nitride (g-C3N4) for visible-light–driven pollutant degradation by constructing a novel Cu3P/Zn0.8Cd0.2S/g-C3N4 ternary nanocomposite. The synthesis of Cu3P/Zn0.8Cd0.2S/g-C3N4 is conducted by a facile hydrothermal procedure. The structural characteristics, morphology, and photocatalytic properties of the composite were evaluated using XRD, FTIR, XPS, BET, FE-SEM, EDS, TEM, UV–Vis DRS, PL, EIS, photocurrent response, Mott-Schottky, and UV–Vis spectroscopy. The photocatalytic degradation of the aqueous solution of methylene blue was performed for 3 h under the irradiation of an LED lamp (100 W, 400–700 nm). The 5%-Cu3P/Zn0.8Cd0.2S/g-C3N4 composite exhibited the highest photocatalytic efficiency, achieving a 95.64% degradation of MB within 180 min, and 72.09% in 30 min, with an apparent rate constant of 0.0131 min−1, substantially outperforming the individual components (58.55% for g-C3N4, 58.63% for Zn0.8Cd0.2S, and 70.15% for Cu3P within 180 min). The improved photocatalytic capability of Cu3P/Zn0.8Cd0.2S/g-C3N4 is mainly attributed to the construction of a dual Z-scheme heterojunction between g-C3N4, Zn0.8Cd0.2S, and Cu3P, promoting both the separation and movement of photoexcited charge transporters. This study demonstrates the potential of developing Cu3P/Zn0.8Cd0.2S/g-C3N4 heterojunction as a noble-metal-free and cost-effective photocatalyst for wastewater treatment, suggesting its applicability for other purposes such as water splitting, CO2 reduction, and antibacterial activity.

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来源期刊
Ionics
Ionics 化学-电化学
CiteScore
5.30
自引率
7.10%
发文量
427
审稿时长
2.2 months
期刊介绍: Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.
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