磁控溅射制备纳米cu膜/透明木材的微观结构和电导率研究

IF 3 2区 农林科学 Q1 FORESTRY
Xiaochun Guo, Fengpei Yuan, Xin Li, Jingkui Li
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引用次数: 0

摘要

将金属与透明木材相结合,赋予其良好的导电性,对于提高木材的功能和扩大应用领域具有重要的现实意义。本文以巴尔沙木为基材,采用脱木质素处理和环氧树脂浸渍法制备透明木材,并采用磁控溅射法制备纳米cu膜/透明木材复合材料。对复合材料的微观结构、表面形貌、疏水性和电导率进行了表征和测试。结果表明:当溅射时间达到30 min时,透明木材表面几乎完全被纳米cu膜覆盖,样品表面形成“片状”致密纳米cu膜,实现了透明木材表面的金属化;在2θ = 43.3°、50.4°和74.1°附近出现金属铜Cu(111)、Cu(200)和Cu(220)衍射峰;透明木材表面Cu元素含量达91.85%;平行晶粒电阻为1.24 Ω/sq,跨晶粒电阻为1.62 Ω/sq,由此可见,利用磁控溅射这一纯物理方法将金属材料与透明木材复合,成功制备了表面为方形且电阻值低于2 Ω/sq的纳米cu膜/透明木材,这也为现代电子、建筑和装饰材料等相关领域的应用开辟了更多的可能性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The study of microstructure and electrical conductivity of nano-Cu film/transparent wood constructed based on magnetron sputtering

The study of microstructure and electrical conductivity of nano-Cu film/transparent wood constructed based on magnetron sputtering

Combining metal with transparent wood to give it good electrical conductivity is of great practical significance for the functional improvement of wood and the expansion of application areas. In this paper, transparent wood was prepared by delignification treatment and impregnation of epoxy resin with balsa wood as the substrate, and nano-Cu film/transparent wood composites were prepared by magnetron sputtering. The microstructure, surface morphology, hydrophobicity and electrical conductivity of the composites were characterized and tested. The results show that: when the sputtering time reaches 30 min, the surface of transparent wood is almost completely covered by the nano-Cu film, and a “sheet-like” dense nano-Cu film is formed on the surface of the sample, which realizes the metallization of the surface of the transparent wood; at 2θ equal to the vicinity of 43.3°, 50.4° and 74.1°, the metallic copper Cu (111), Cu(200) and Cu(220) diffraction peaks appeared; the Cu element content on the surface of transparent wood reached 91.85%; the parallel to grain resistance is 1.24 Ω/sq and the across grain resistance is 1.62 Ω/sq, which can be seen that the composite of metallic material and transparent wood using magnetron sputtering, a purely physical method, successfully prepares the nano-Cu film/transparent wood with the surface square with the resistance value lower than 2 Ω/sq, which also has opened up more possibilities for applications in modern electronics, architectural and decorative materials, and other related fields.

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来源期刊
Wood Science and Technology
Wood Science and Technology 工程技术-材料科学:纸与木材
CiteScore
5.90
自引率
5.90%
发文量
75
审稿时长
3 months
期刊介绍: Wood Science and Technology publishes original scientific research results and review papers covering the entire field of wood material science, wood components and wood based products. Subjects are wood biology and wood quality, wood physics and physical technologies, wood chemistry and chemical technologies. Latest advances in areas such as cell wall and wood formation; structural and chemical composition of wood and wood composites and their property relations; physical, mechanical and chemical characterization and relevant methodological developments, and microbiological degradation of wood and wood based products are reported. Topics related to wood technology include machining, gluing, and finishing, composite technology, wood modification, wood mechanics, creep and rheology, and the conversion of wood into pulp and biorefinery products.
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