{"title":"硝基芳烃的光化学硼化反应","authors":"Kaiyao Feng, , , Shuai Tang, , , Jinxi Cao, , , Linghe Li, , , Xiaoyun Hu*, , and , Hua Zhang*, ","doi":"10.1021/acs.joc.5c01636","DOIUrl":null,"url":null,"abstract":"<p >We describe a straightforward light-driven strategy for transforming nitroarenes to aryl boronic esters. This transformation proceeds under mild conditions at ambient temperature and tolerates a wide variety of functional groups. The approach offers an operationally simple and practical alternative for preparing aryl boronic esters directly from nitroarenes, which are readily available and inexpensive starting materials.</p>","PeriodicalId":57,"journal":{"name":"Journal of Organic Chemistry","volume":"90 40","pages":"14172–14176"},"PeriodicalIF":3.6000,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Photochemical Borylation of Nitroarenes\",\"authors\":\"Kaiyao Feng, , , Shuai Tang, , , Jinxi Cao, , , Linghe Li, , , Xiaoyun Hu*, , and , Hua Zhang*, \",\"doi\":\"10.1021/acs.joc.5c01636\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >We describe a straightforward light-driven strategy for transforming nitroarenes to aryl boronic esters. This transformation proceeds under mild conditions at ambient temperature and tolerates a wide variety of functional groups. The approach offers an operationally simple and practical alternative for preparing aryl boronic esters directly from nitroarenes, which are readily available and inexpensive starting materials.</p>\",\"PeriodicalId\":57,\"journal\":{\"name\":\"Journal of Organic Chemistry\",\"volume\":\"90 40\",\"pages\":\"14172–14176\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2025-09-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Organic Chemistry\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.joc.5c01636\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Organic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.joc.5c01636","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
We describe a straightforward light-driven strategy for transforming nitroarenes to aryl boronic esters. This transformation proceeds under mild conditions at ambient temperature and tolerates a wide variety of functional groups. The approach offers an operationally simple and practical alternative for preparing aryl boronic esters directly from nitroarenes, which are readily available and inexpensive starting materials.
期刊介绍:
Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.