{"title":"具有轴相关传导极性的材料的磁场指南","authors":"Tianze Song, Joshua E. Goldberger","doi":"10.1021/acs.chemmater.5c01707","DOIUrl":null,"url":null,"abstract":"Most electronic materials uniformly exhibit either dominant p- or n-type conduction along all crystallographic directions. However, there is an emerging class of materials in which either dominant p- or n-type conduction is observed depending on the crystallographic direction. This phenomenon is referred to as axis-dependent conduction polarity (ADCP) and has been experimentally detected across many different classes of materials. In this Review, we start by establishing the band structure origins and signatures of this phenomenon. Then, we thoroughly detail each material in which ADCP has been observed. We provide a chemical understanding of why ADCP occurs in these materials and show that closely related isostructural and isoelectronic phases will also exhibit this effect. This zoological survey of ADCP materials will serve as an important reference as electronic device concepts exploiting this effect arise.","PeriodicalId":33,"journal":{"name":"Chemistry of Materials","volume":"93 1","pages":""},"PeriodicalIF":7.0000,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Field Guide to Materials with Axis-Dependent Conduction Polarity\",\"authors\":\"Tianze Song, Joshua E. Goldberger\",\"doi\":\"10.1021/acs.chemmater.5c01707\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Most electronic materials uniformly exhibit either dominant p- or n-type conduction along all crystallographic directions. However, there is an emerging class of materials in which either dominant p- or n-type conduction is observed depending on the crystallographic direction. This phenomenon is referred to as axis-dependent conduction polarity (ADCP) and has been experimentally detected across many different classes of materials. In this Review, we start by establishing the band structure origins and signatures of this phenomenon. Then, we thoroughly detail each material in which ADCP has been observed. We provide a chemical understanding of why ADCP occurs in these materials and show that closely related isostructural and isoelectronic phases will also exhibit this effect. This zoological survey of ADCP materials will serve as an important reference as electronic device concepts exploiting this effect arise.\",\"PeriodicalId\":33,\"journal\":{\"name\":\"Chemistry of Materials\",\"volume\":\"93 1\",\"pages\":\"\"},\"PeriodicalIF\":7.0000,\"publicationDate\":\"2025-09-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry of Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.chemmater.5c01707\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry of Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acs.chemmater.5c01707","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
A Field Guide to Materials with Axis-Dependent Conduction Polarity
Most electronic materials uniformly exhibit either dominant p- or n-type conduction along all crystallographic directions. However, there is an emerging class of materials in which either dominant p- or n-type conduction is observed depending on the crystallographic direction. This phenomenon is referred to as axis-dependent conduction polarity (ADCP) and has been experimentally detected across many different classes of materials. In this Review, we start by establishing the band structure origins and signatures of this phenomenon. Then, we thoroughly detail each material in which ADCP has been observed. We provide a chemical understanding of why ADCP occurs in these materials and show that closely related isostructural and isoelectronic phases will also exhibit this effect. This zoological survey of ADCP materials will serve as an important reference as electronic device concepts exploiting this effect arise.
期刊介绍:
The journal Chemistry of Materials focuses on publishing original research at the intersection of materials science and chemistry. The studies published in the journal involve chemistry as a prominent component and explore topics such as the design, synthesis, characterization, processing, understanding, and application of functional or potentially functional materials. The journal covers various areas of interest, including inorganic and organic solid-state chemistry, nanomaterials, biomaterials, thin films and polymers, and composite/hybrid materials. The journal particularly seeks papers that highlight the creation or development of innovative materials with novel optical, electrical, magnetic, catalytic, or mechanical properties. It is essential that manuscripts on these topics have a primary focus on the chemistry of materials and represent a significant advancement compared to prior research. Before external reviews are sought, submitted manuscripts undergo a review process by a minimum of two editors to ensure their appropriateness for the journal and the presence of sufficient evidence of a significant advance that will be of broad interest to the materials chemistry community.