稳健性噻唑聚醚金配合物的直接方法：丙酰胺环异构化的有效催化剂

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-09-25 DOI:10.1039/d5dt02258d

Savvas Chalkidis, Nikolaos Tsoureas, Steven P Nolan, Georgios C Vougioukalakis

引用次数: 0

摘要

本文介绍了一种新型噻唑聚吡啶金配合物的简单合成方法。尽管它们的空间保护作用降低，但这些配合物在hfip辅助的丙烯酰胺环异构化中表现出优异的稳定性和高的催化活性。报道了一种新型稳定的噻唑烷基金烷氧配合物的合成及其催化活性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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A straightforward approach to robust thiazolylidene gold complexes: Efficient catalysts for propargylamide cycloisomerizations

The straightforward synthesis of new thiazolylidene gold complexes is described. Despite their decreased steric protection, these complexes demonstrate excellent stability and high catalytic activity in the HFIP-assisted cycloisomerization of propargylamides. The synthesis and catalytic activity of a novel, stable thiazolylidene gold alkoxide complex is also reported.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.