{"title":"风力涡轮机叶片的可持续回收:通过循环流化床技术回收玻璃纤维。","authors":"Senxiang Liu,Ke Ren,Shaoqi Kong,Suxia Ma,Ruixue Feng","doi":"10.1021/acs.langmuir.5c03798","DOIUrl":null,"url":null,"abstract":"This study investigates the application of circulating fluidized bed (CFB) oxidative pyrolysis for the recovery of glass fibers from decommissioned wind turbine blades (WTB). XPS analysis revealed that increasing oxidative pyrolysis temperature led to a progressive reduction in C-C bonds and an increase in polar surface groups such as C-OH and O─C═O, indicating enhanced surface oxidation and degradation of the carbon backbone. SEM images showed that surface morphology deteriorated at high temperatures, with increased cracking and contamination, whereas moderate oxidative pyrolysis conditions preserved smoother surfaces. Samples combusted with a temperature range of 600-700 °C (R2) yielded the most favorable balance between surface functionalization and structural integrity, as evidenced by the retention of key Si-C and Si-O-Si frameworks. R2 exhibited the highest tensile strength (0.295 GPa) and strength recovery rate (33.5%) among recycled samples. In contrast, lower temperatures showed signs of incomplete matrix decomposition, while higher temperatures underwent excessive thermal damage, impairing their mechanical performance. These findings highlight the critical role of oxidative pyrolysis temperature in governing the physicochemical and mechanical properties of recycled glass fibers and demonstrate that a controlled CFB process can enable the recovery of high-quality fibers suitable for reuse.","PeriodicalId":50,"journal":{"name":"Langmuir","volume":"100 1","pages":""},"PeriodicalIF":3.9000,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sustainable Recycling of Wind Turbine Blades: Glass Fiber Recovery through CFB Technology.\",\"authors\":\"Senxiang Liu,Ke Ren,Shaoqi Kong,Suxia Ma,Ruixue Feng\",\"doi\":\"10.1021/acs.langmuir.5c03798\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This study investigates the application of circulating fluidized bed (CFB) oxidative pyrolysis for the recovery of glass fibers from decommissioned wind turbine blades (WTB). XPS analysis revealed that increasing oxidative pyrolysis temperature led to a progressive reduction in C-C bonds and an increase in polar surface groups such as C-OH and O─C═O, indicating enhanced surface oxidation and degradation of the carbon backbone. SEM images showed that surface morphology deteriorated at high temperatures, with increased cracking and contamination, whereas moderate oxidative pyrolysis conditions preserved smoother surfaces. Samples combusted with a temperature range of 600-700 °C (R2) yielded the most favorable balance between surface functionalization and structural integrity, as evidenced by the retention of key Si-C and Si-O-Si frameworks. R2 exhibited the highest tensile strength (0.295 GPa) and strength recovery rate (33.5%) among recycled samples. In contrast, lower temperatures showed signs of incomplete matrix decomposition, while higher temperatures underwent excessive thermal damage, impairing their mechanical performance. These findings highlight the critical role of oxidative pyrolysis temperature in governing the physicochemical and mechanical properties of recycled glass fibers and demonstrate that a controlled CFB process can enable the recovery of high-quality fibers suitable for reuse.\",\"PeriodicalId\":50,\"journal\":{\"name\":\"Langmuir\",\"volume\":\"100 1\",\"pages\":\"\"},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2025-09-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Langmuir\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.langmuir.5c03798\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Langmuir","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.langmuir.5c03798","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Sustainable Recycling of Wind Turbine Blades: Glass Fiber Recovery through CFB Technology.
This study investigates the application of circulating fluidized bed (CFB) oxidative pyrolysis for the recovery of glass fibers from decommissioned wind turbine blades (WTB). XPS analysis revealed that increasing oxidative pyrolysis temperature led to a progressive reduction in C-C bonds and an increase in polar surface groups such as C-OH and O─C═O, indicating enhanced surface oxidation and degradation of the carbon backbone. SEM images showed that surface morphology deteriorated at high temperatures, with increased cracking and contamination, whereas moderate oxidative pyrolysis conditions preserved smoother surfaces. Samples combusted with a temperature range of 600-700 °C (R2) yielded the most favorable balance between surface functionalization and structural integrity, as evidenced by the retention of key Si-C and Si-O-Si frameworks. R2 exhibited the highest tensile strength (0.295 GPa) and strength recovery rate (33.5%) among recycled samples. In contrast, lower temperatures showed signs of incomplete matrix decomposition, while higher temperatures underwent excessive thermal damage, impairing their mechanical performance. These findings highlight the critical role of oxidative pyrolysis temperature in governing the physicochemical and mechanical properties of recycled glass fibers and demonstrate that a controlled CFB process can enable the recovery of high-quality fibers suitable for reuse.
期刊介绍:
Langmuir is an interdisciplinary journal publishing articles in the following subject categories:
Colloids: surfactants and self-assembly, dispersions, emulsions, foams
Interfaces: adsorption, reactions, films, forces
Biological Interfaces: biocolloids, biomolecular and biomimetic materials
Materials: nano- and mesostructured materials, polymers, gels, liquid crystals
Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry
Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals
However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do?
Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*.
This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).