风力涡轮机叶片的可持续回收:通过循环流化床技术回收玻璃纤维。

IF 3.9 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Senxiang Liu,Ke Ren,Shaoqi Kong,Suxia Ma,Ruixue Feng
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引用次数: 0

摘要

研究了循环流化床(CFB)氧化热解技术在回收报废风电叶片玻璃纤维中的应用。XPS分析显示,氧化热解温度升高导致C-C键逐渐减少,表面极性基团如C- oh和O─C = O增加,表明表面氧化和碳主链降解增强。扫描电镜图像显示,高温下表面形貌恶化,开裂和污染增加,而适度的氧化热解条件保留了光滑的表面。在600-700°C (R2)温度范围内燃烧的样品在表面功能化和结构完整性之间取得了最有利的平衡,关键的Si-C和Si-O-Si框架的保留证明了这一点。R2具有最高的抗拉强度(0.295 GPa)和强度回收率(33.5%)。相比之下,较低的温度显示出基体不完全分解的迹象,而较高的温度则经历了过度的热损伤,损害了它们的机械性能。这些发现强调了氧化热解温度在控制再生玻璃纤维的物理化学和机械性能方面的关键作用,并表明受控的CFB工艺可以回收适合重复使用的高质量纤维。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Sustainable Recycling of Wind Turbine Blades: Glass Fiber Recovery through CFB Technology.
This study investigates the application of circulating fluidized bed (CFB) oxidative pyrolysis for the recovery of glass fibers from decommissioned wind turbine blades (WTB). XPS analysis revealed that increasing oxidative pyrolysis temperature led to a progressive reduction in C-C bonds and an increase in polar surface groups such as C-OH and O─C═O, indicating enhanced surface oxidation and degradation of the carbon backbone. SEM images showed that surface morphology deteriorated at high temperatures, with increased cracking and contamination, whereas moderate oxidative pyrolysis conditions preserved smoother surfaces. Samples combusted with a temperature range of 600-700 °C (R2) yielded the most favorable balance between surface functionalization and structural integrity, as evidenced by the retention of key Si-C and Si-O-Si frameworks. R2 exhibited the highest tensile strength (0.295 GPa) and strength recovery rate (33.5%) among recycled samples. In contrast, lower temperatures showed signs of incomplete matrix decomposition, while higher temperatures underwent excessive thermal damage, impairing their mechanical performance. These findings highlight the critical role of oxidative pyrolysis temperature in governing the physicochemical and mechanical properties of recycled glass fibers and demonstrate that a controlled CFB process can enable the recovery of high-quality fibers suitable for reuse.
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来源期刊
Langmuir
Langmuir 化学-材料科学:综合
CiteScore
6.50
自引率
10.30%
发文量
1464
审稿时长
2.1 months
期刊介绍: Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
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