封面特征：与亚氨基吡啶配体的单金属和双金属[Mn(CO)3]配合物用于氢气和合成气生产（ChemCatChem 15/2025）

IF 3.9 3区化学 Q2 CHEMISTRY, PHYSICAL

ChemCatChem Pub Date : 2025-08-07 DOI:10.1002/cctc.70239

Vera V. Khrizanforova, Robert R. Fayzullin, Ruslan B. Zaripov, Tatiana P. Gerasimova, Vladimir I. Morozov, Evgeniya B. Krasovskaya, Yulia H. Budnikova

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引用次数: 0

摘要

覆盖特征说明了两种新型单金属和双金属三羰基锰(I)配合物与苊基氨基吡啶配体在电催化CO2还原反应（CO2RR）和析氢反应（HER）中的效率。研究发现，单体锰配合物以配体中心的方式还原，在这些反应（TON， TOF，过电位）中表现出比金属中心还原的二聚体MnI配合物更高的效率。更多信息可以在V. V. Khrizanforova， Yu的研究文章中找到。H. Budnikova和同事（DOI: 10.1002/cctc.202500078）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Cover Feature: Mono- and Dimetallic [Mn(CO)3] Complexes with the Iminopyridine Ligand for Both Hydrogen and Syngas Productions (ChemCatChem 15/2025)

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Cover Feature: Mono- and Dimetallic [Mn(CO)3] Complexes with the Iminopyridine Ligand for Both Hydrogen and Syngas Productions (ChemCatChem 15/2025)

The Cover Feature illustrates the efficiency of two novel mono- and dimetallic tricarbonyl manganese(I) complexes with an acenaphthene-based iminopyridine ligand in electrocatalytic CO₂ reduction reaction (CO₂RR) and hydrogen evolution reaction (HER). It was found that the monomeric manganese complex is reduced in a ligand-centered manner and shows much higher efficiency in these reactions (TON, TOF, overpotential) compared to the metal-centered reduced dimeric Mn^I complex. More information can be found in the Research Article by V. V. Khrizanforova, Yu. H. Budnikova and co-workers (DOI: 10.1002/cctc.202500078).

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来源期刊

ChemCatChem 化学-物理化学

CiteScore

8.10

自引率

4.40%

发文量

511

审稿时长

1.3 months

期刊介绍： With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.