钴钼浸渍对Y型沸石结构及酸性的影响

IF 1 4区 化学 Q4 SPECTROSCOPY
Roufaida Mahdi, Hidaya Izza, Oussama Bacha, Ayoub Magroud
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引用次数: 0

摘要

沸石具有Brønsted酸位和浸渍金属在其孔隙中,这使得它对催化转化非常有利,这需要金属和酸性活性位点的存在,如加氢异构化和加氢裂化反应。本研究探讨了钴(Co)和钼(Mo)浸渍对Y型沸石结构和酸性性能的影响。采用不同金属浓度的湿浸渍法合成了一系列como - Y型沸石催化剂。通过x射线衍射、傅里叶红外光谱(FTIR)和吡啶红外光谱(FTIR)表征表明,Co和Mo的引入改变了Brønsted和Lewis酸位的分布和强度,而Y型分子筛骨架的结晶度保持不变。值得注意的是,Co6Mo催化剂表现出最佳的Lewis/Brønsted酸比,突出了这些材料在双功能催化应用中的潜力。这些发现有助于理解金属负载与酸性质之间的相互作用,为进一步研究催化性能奠定基础。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Impact of Cobalt and Molybdenum Impregnation on the Structural and Acidic Properties of Zeolite Y

Zeolite’s possession of Brønsted acid sites and impregnated metals in its pores renders it highly advantageous for catalytic transformations that necessitate the presence of both metallic and acidic active sites such as hydroisomerization and hydrocracking reactions. This study explores the influence of cobalt (Co) and molybdenum (Mo) impregnation on the structural and acidic properties of zeolite Y. A series of CoMo–zeolite Y catalysts was synthesized using the wet impregnation method with varying metal concentrations. Characterization using X-ray diffraction, Fourier-transform infrared spectroscopy (FTIR), and pyridine–FTIR revealed that the introduction of Co and Mo modified the distribution and strength of Brønsted and Lewis acid sites, while the crystallinity of the zeolite Y framework was preserved. Notably, the Co6Mo catalyst exhibited an optimal Lewis/Brønsted acid ratio, highlighting the potential of these materials for bifunctional catalytic applications. These findings contribute to understanding the interplay between metal loading and acid properties, laying the groundwork for future studies on catalytic performance.

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来源期刊
CiteScore
1.30
自引率
14.30%
发文量
145
审稿时长
2.5 months
期刊介绍: Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.
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