{"title":"麦麸/Fe3O4/β-环糊精复合吸附剂对s -西酞普兰的吸附研究","authors":"Yasaman Karim Khani, Ali Moghimi, Malak Hekmati","doi":"10.1007/s10812-025-01986-y","DOIUrl":null,"url":null,"abstract":"<p>This study focuses on the synthesis of a biocompatible magnetic nanosorbent, modified with β-cyclodextrin (β-CD), using wheat bran (WB) for the adsorption of the drug S-citalopram (S-CIT). Various characterization techniques, including FTIR, SEM, XRD, and VSM, confirmed the successful creation of the wheat bran/Fe<sub>3</sub>O<sub>4</sub>/β-cyclodextrin (WB/Fe<sub>3</sub>O<sub>4</sub>/β-CD) nanoadsorbent and its effective interaction with S-CIT. Optimization of parameters such as pH and temperature led to an impressive adsorption efficiency of up to 94%, with a maximum adsorption capacity of 91.74 mg/g under optimal conditions. A calibration curve was established for S-CIT concentrations ranging from 0.2 to 50 μM, yielding a detection limit of 0.050 μM. Thermodynamic and kinetic studies indicated that the adsorption process is exothermic and follows the characteristics of chemisorption. Additionally, it adhered to the Langmuir isotherm model and the pseudo-second-order kinetic model.</p>","PeriodicalId":609,"journal":{"name":"Journal of Applied Spectroscopy","volume":"92 4","pages":"907 - 916"},"PeriodicalIF":1.0000,"publicationDate":"2025-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Novel Adsorbent Composed of Wheat Bran/Fe3O4/β-Cyclodextrin for the Removal of S-Citalopram from Aqueous Samples\",\"authors\":\"Yasaman Karim Khani, Ali Moghimi, Malak Hekmati\",\"doi\":\"10.1007/s10812-025-01986-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This study focuses on the synthesis of a biocompatible magnetic nanosorbent, modified with β-cyclodextrin (β-CD), using wheat bran (WB) for the adsorption of the drug S-citalopram (S-CIT). Various characterization techniques, including FTIR, SEM, XRD, and VSM, confirmed the successful creation of the wheat bran/Fe<sub>3</sub>O<sub>4</sub>/β-cyclodextrin (WB/Fe<sub>3</sub>O<sub>4</sub>/β-CD) nanoadsorbent and its effective interaction with S-CIT. Optimization of parameters such as pH and temperature led to an impressive adsorption efficiency of up to 94%, with a maximum adsorption capacity of 91.74 mg/g under optimal conditions. A calibration curve was established for S-CIT concentrations ranging from 0.2 to 50 μM, yielding a detection limit of 0.050 μM. Thermodynamic and kinetic studies indicated that the adsorption process is exothermic and follows the characteristics of chemisorption. Additionally, it adhered to the Langmuir isotherm model and the pseudo-second-order kinetic model.</p>\",\"PeriodicalId\":609,\"journal\":{\"name\":\"Journal of Applied Spectroscopy\",\"volume\":\"92 4\",\"pages\":\"907 - 916\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2025-09-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Spectroscopy\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10812-025-01986-y\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"SPECTROSCOPY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10812-025-01986-y","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
Novel Adsorbent Composed of Wheat Bran/Fe3O4/β-Cyclodextrin for the Removal of S-Citalopram from Aqueous Samples
This study focuses on the synthesis of a biocompatible magnetic nanosorbent, modified with β-cyclodextrin (β-CD), using wheat bran (WB) for the adsorption of the drug S-citalopram (S-CIT). Various characterization techniques, including FTIR, SEM, XRD, and VSM, confirmed the successful creation of the wheat bran/Fe3O4/β-cyclodextrin (WB/Fe3O4/β-CD) nanoadsorbent and its effective interaction with S-CIT. Optimization of parameters such as pH and temperature led to an impressive adsorption efficiency of up to 94%, with a maximum adsorption capacity of 91.74 mg/g under optimal conditions. A calibration curve was established for S-CIT concentrations ranging from 0.2 to 50 μM, yielding a detection limit of 0.050 μM. Thermodynamic and kinetic studies indicated that the adsorption process is exothermic and follows the characteristics of chemisorption. Additionally, it adhered to the Langmuir isotherm model and the pseudo-second-order kinetic model.
期刊介绍：
Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.
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