一氧化硼是一种一维聚合物

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-09-25 DOI:10.1039/d5cc04723d

Joseph Frederick Thuma, Carl Henry Fleischer III, Frédéric Perras, Rana Biswas, Levi Stanley, Wenyu Huang

{"title":"一氧化硼是一种一维聚合物","authors":"Joseph Frederick Thuma, Carl Henry Fleischer III, Frédéric Perras, Rana Biswas, Levi Stanley, Wenyu Huang","doi":"10.1039/d5cc04723d","DOIUrl":null,"url":null,"abstract":"It was recently reported that boron monoxide (BO) is formed through the cross-linking of B4O2 structural building units. Multiple theoretical phases agree with this description. Using pycnometry, multidimensional 17O NMR spectroscopy, and plane-wave DFT calculations we determined the likely polymorph to be a one-dimensional polymer initially proposed in 1955.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"28 1","pages":""},"PeriodicalIF":4.2000,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Boron Monoxide is a One-Dimensional Polymer\",\"authors\":\"Joseph Frederick Thuma, Carl Henry Fleischer III, Frédéric Perras, Rana Biswas, Levi Stanley, Wenyu Huang\",\"doi\":\"10.1039/d5cc04723d\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"It was recently reported that boron monoxide (BO) is formed through the cross-linking of B4O2 structural building units. Multiple theoretical phases agree with this description. Using pycnometry, multidimensional 17O NMR spectroscopy, and plane-wave DFT calculations we determined the likely polymorph to be a one-dimensional polymer initially proposed in 1955.\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"28 1\",\"pages\":\"\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-09-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5cc04723d\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc04723d","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

最近有报道称，一氧化硼（BO）是通过B4O2结构单元的交联形成的。许多理论阶段都符合这一描述。利用体积学、多维17O核磁共振波谱和平面波DFT计算，我们确定了可能的多晶型是1955年最初提出的一维聚合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Boron Monoxide is a One-Dimensional Polymer

It was recently reported that boron monoxide (BO) is formed through the cross-linking of B4O2 structural building units. Multiple theoretical phases agree with this description. Using pycnometry, multidimensional 17O NMR spectroscopy, and plane-wave DFT calculations we determined the likely polymorph to be a one-dimensional polymer initially proposed in 1955.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.