Phosphaza-norbornanes

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-09-24 DOI:10.1039/d5dt02134k

Joseph Nazak, Michael A. Land, Jason Douglas Masuda, Saurabh Chitnis

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引用次数: 0

摘要

首次明确分离出降冰片烯磷。这些PN框架具有双环[2.2.1]庚烷骨架和桥头堡P（III）位点，可以通过从伯胺开始的模块化缩合反应制备。它们的分子和电子结构、稳定性和应变能与密切相关的PN或碳氢双环体系进行了比较。

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Phosphaza-norbornanes

The first definitive isolation of phosphaza-norbornanes is reported. These PN frameworks feature a bicyclo[2.2.1]heptane skeleton with bridgehead P(III) sites and can be made via a modular condensation reaction starting from primary amines. Their molecular and electronic structures, stability, and strain energies are compared with closely related PN or hydrocarbon bicyclic systems.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.