{"title":"用改性生物炭去除水溶液中的阴离子和阳离子染料:表征、等温线、动力学和热力学研究。","authors":"Emel Moral, Fethiye Göde, Okan Bayram","doi":"10.1080/15226514.2025.2563149","DOIUrl":null,"url":null,"abstract":"<p><p>Anionic and cationic dyes are two basic types of dyestuffs classified based on their chemical structure and electrical charge. These dyes are used to give color in industrial and application areas such as textiles, paper, food, and ink. The untreated discharge of these dyestuffs into clean water sources poses a significant danger to living organisms. In this study, <i>Gypsophila arrostii var nebulosa</i> (GA) was used to prepare biochar (b-GA), which was then modified (mb-GA). Then, the adsorption properties on methyl blue (MeB), an anionic dye, and methylene blue (MB), a cationic dye, were investigated. Characterization of the biochar showed it to be amorphous. When the adsorption processes were analyzed, it was determined that the process was pseudo-second-order, endothermic, and fit the Langmuir isotherm model. The maximum adsorption capacity (q<sub>max</sub>) was found to be 17.065 mg/g for b-GA-MeB, 44.444 mg/g for mb-GA-MeB, 28.011 mg/g for b-GA-MB, and 49.505 mg/g for mb-GA-MB.</p>","PeriodicalId":14235,"journal":{"name":"International Journal of Phytoremediation","volume":" ","pages":"1-12"},"PeriodicalIF":3.1000,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Removal of anionic and cationic dye from aqueous solutions with modified biochar <i>Gypsophila arrostii var nebulosa</i>: characterization, isotherm, kinetics, thermodynamics studies.\",\"authors\":\"Emel Moral, Fethiye Göde, Okan Bayram\",\"doi\":\"10.1080/15226514.2025.2563149\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Anionic and cationic dyes are two basic types of dyestuffs classified based on their chemical structure and electrical charge. These dyes are used to give color in industrial and application areas such as textiles, paper, food, and ink. The untreated discharge of these dyestuffs into clean water sources poses a significant danger to living organisms. In this study, <i>Gypsophila arrostii var nebulosa</i> (GA) was used to prepare biochar (b-GA), which was then modified (mb-GA). Then, the adsorption properties on methyl blue (MeB), an anionic dye, and methylene blue (MB), a cationic dye, were investigated. Characterization of the biochar showed it to be amorphous. When the adsorption processes were analyzed, it was determined that the process was pseudo-second-order, endothermic, and fit the Langmuir isotherm model. The maximum adsorption capacity (q<sub>max</sub>) was found to be 17.065 mg/g for b-GA-MeB, 44.444 mg/g for mb-GA-MeB, 28.011 mg/g for b-GA-MB, and 49.505 mg/g for mb-GA-MB.</p>\",\"PeriodicalId\":14235,\"journal\":{\"name\":\"International Journal of Phytoremediation\",\"volume\":\" \",\"pages\":\"1-12\"},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2025-09-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Phytoremediation\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.1080/15226514.2025.2563149\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Phytoremediation","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1080/15226514.2025.2563149","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Removal of anionic and cationic dye from aqueous solutions with modified biochar Gypsophila arrostii var nebulosa: characterization, isotherm, kinetics, thermodynamics studies.
Anionic and cationic dyes are two basic types of dyestuffs classified based on their chemical structure and electrical charge. These dyes are used to give color in industrial and application areas such as textiles, paper, food, and ink. The untreated discharge of these dyestuffs into clean water sources poses a significant danger to living organisms. In this study, Gypsophila arrostii var nebulosa (GA) was used to prepare biochar (b-GA), which was then modified (mb-GA). Then, the adsorption properties on methyl blue (MeB), an anionic dye, and methylene blue (MB), a cationic dye, were investigated. Characterization of the biochar showed it to be amorphous. When the adsorption processes were analyzed, it was determined that the process was pseudo-second-order, endothermic, and fit the Langmuir isotherm model. The maximum adsorption capacity (qmax) was found to be 17.065 mg/g for b-GA-MeB, 44.444 mg/g for mb-GA-MeB, 28.011 mg/g for b-GA-MB, and 49.505 mg/g for mb-GA-MB.
期刊介绍:
The International Journal of Phytoremediation (IJP) is the first journal devoted to the publication of laboratory and field research describing the use of plant systems to solve environmental problems by enabling the remediation of soil, water, and air quality and by restoring ecosystem services in managed landscapes. Traditional phytoremediation has largely focused on soil and groundwater clean-up of hazardous contaminants. Phytotechnology expands this umbrella to include many of the natural resource management challenges we face in cities, on farms, and other landscapes more integrated with daily public activities. Wetlands that treat wastewater, rain gardens that treat stormwater, poplar tree plantings that contain pollutants, urban tree canopies that treat air pollution, and specialized plants that treat decommissioned mine sites are just a few examples of phytotechnologies.