Eveline H. Tiekink, Matthijs W. Kragtwijk, Trevor A. Hamlin
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Cover Feature: Small Molecule Activation by Metallylenes and their Follow-Up Reactions (ChemistryEurope 5/2025)
Blurring the boundaries between main-group and transition metal chemistry, Group 14 metallylenes offer a tunable, earth-abundant platform for catalysis. Once the domain of d-block elements, transition metal-like reactivity is now within reach—unlocking new avenues for sustainable small-molecule activation and follow-up reactions through ligand optimization and quantum chemical design. More information can be found in the Review by T. A. Hamlin and co-workers (DOI: 10.1002/ceur.202500119).