封面特征:增加锥体硼烷的刘易斯酸度:阳离子9-硼-1-氮杂三烯作为强硼刘易斯超强酸(化学欧洲5/2025)

ChemistryEurope Pub Date : 2025-09-23 DOI:10.1002/ceur.70076
Nicolas Niessen, Loïc Mineur, Aurélien Chardon, Arnaud Osi, Abel Idrice Adjieufack, Damien Mahaut, Nikolay Tumanov, Johan Wouters, Benoît Champagne, Guillaume Berionni
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引用次数: 0

摘要

封面特征说明了硼化学中刘易斯酸度的新维度的发现。在他们的研究文章(DOI: 10.1002/ceur)中。202500100), G. Berionni及其同事解释了他们如何开发新的金字塔型硼刘易斯超酸,该超酸含有一个吡啶/吡啶单元,可以随时切换刘易斯酸度和电荷。观察到硼与弱配位阴离子之间的新配位模式,并分离出若干含硼、含氮的蒽基、三甲烯基和双三甲烯基序。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Cover Feature: Increasing the Lewis Acidity of Pyramidal Boranes: Cationic 9-Bora-1-Azatriptycenes as Strong Boron Lewis Superacids (ChemistryEurope 5/2025)

Cover Feature: Increasing the Lewis Acidity of Pyramidal Boranes: Cationic 9-Bora-1-Azatriptycenes as Strong Boron Lewis Superacids (ChemistryEurope 5/2025)

The Cover Feature illustrates the discovery of new dimensions of Lewis acidity in boron chemistry. In their Research Article (DOI: 10.1002/ceur.202500100), G. Berionni and co-workers explain how they developed new pyramidal boron Lewis superacids containing a pyridine/pyridinium unit ready to be switched in Lewis acidity and charge. New coordination modes between boron and weakly coordinating anions are observed and several boron and nitrogen containing anthracene, triptycene and bis-triptycene motifs, which are represented on the image, have been isolated.

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