M.R. Akbarpour, F. Farajnezhad, A. H. Poureshagh, S. Moniri Javadhesari, H. S. Kim
{"title":"生物医学用掺铜氟羟基磷灰石涂层的合成与表征:同时阳极氧化处理对AZ31合金基体的影响及电沉积过程中超声搅拌的影响","authors":"M.R. Akbarpour, F. Farajnezhad, A. H. Poureshagh, S. Moniri Javadhesari, H. S. Kim","doi":"10.1007/s12540-025-01924-9","DOIUrl":null,"url":null,"abstract":"<div><p>A copper-doped fluorohydroxyapatite (Cu-FHAp) coating was successfully electrodeposited onto anodized and non-anodized AZ31 alloy using a pulse-reverse method combined with ultrasonic agitation. The effects of anodizing and ultrasonic agitation on the performance characteristics of the Cu-FHAp coating deposited on the AZ31 magnesium alloy surface were studied. The results reveal that ultrasonication reduces coating thickness while enhancing uniformity and density. Anodizing increases roughness and diminishes hydrophobicity. Coatings produced under ultrasonic conditions displayed reduced hydrophobicity and improved cell attachment but lower corrosion resistance. In contrast, coatings formed on anodized alloys through stirring achieved optimal characteristics, benefiting from the protective properties of interlayer MgO.</p></div>","PeriodicalId":703,"journal":{"name":"Metals and Materials International","volume":"31 10","pages":"2890 - 2900"},"PeriodicalIF":4.0000,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Characterization of Copper-Doped Fluorohydroxyapatite Coatings for Biomedical Applications: Influence of Simultaneous Anodizing Treatment on AZ31 Alloy Substrate and Ultrasonic Agitation During Electrodeposition Process\",\"authors\":\"M.R. Akbarpour, F. Farajnezhad, A. H. Poureshagh, S. Moniri Javadhesari, H. S. Kim\",\"doi\":\"10.1007/s12540-025-01924-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A copper-doped fluorohydroxyapatite (Cu-FHAp) coating was successfully electrodeposited onto anodized and non-anodized AZ31 alloy using a pulse-reverse method combined with ultrasonic agitation. The effects of anodizing and ultrasonic agitation on the performance characteristics of the Cu-FHAp coating deposited on the AZ31 magnesium alloy surface were studied. The results reveal that ultrasonication reduces coating thickness while enhancing uniformity and density. Anodizing increases roughness and diminishes hydrophobicity. Coatings produced under ultrasonic conditions displayed reduced hydrophobicity and improved cell attachment but lower corrosion resistance. In contrast, coatings formed on anodized alloys through stirring achieved optimal characteristics, benefiting from the protective properties of interlayer MgO.</p></div>\",\"PeriodicalId\":703,\"journal\":{\"name\":\"Metals and Materials International\",\"volume\":\"31 10\",\"pages\":\"2890 - 2900\"},\"PeriodicalIF\":4.0000,\"publicationDate\":\"2025-03-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Metals and Materials International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12540-025-01924-9\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Metals and Materials International","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s12540-025-01924-9","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis and Characterization of Copper-Doped Fluorohydroxyapatite Coatings for Biomedical Applications: Influence of Simultaneous Anodizing Treatment on AZ31 Alloy Substrate and Ultrasonic Agitation During Electrodeposition Process
A copper-doped fluorohydroxyapatite (Cu-FHAp) coating was successfully electrodeposited onto anodized and non-anodized AZ31 alloy using a pulse-reverse method combined with ultrasonic agitation. The effects of anodizing and ultrasonic agitation on the performance characteristics of the Cu-FHAp coating deposited on the AZ31 magnesium alloy surface were studied. The results reveal that ultrasonication reduces coating thickness while enhancing uniformity and density. Anodizing increases roughness and diminishes hydrophobicity. Coatings produced under ultrasonic conditions displayed reduced hydrophobicity and improved cell attachment but lower corrosion resistance. In contrast, coatings formed on anodized alloys through stirring achieved optimal characteristics, benefiting from the protective properties of interlayer MgO.
期刊介绍:
Metals and Materials International publishes original papers and occasional critical reviews on all aspects of research and technology in materials engineering: physical metallurgy, materials science, and processing of metals and other materials. Emphasis is placed on those aspects of the science of materials that are concerned with the relationships among the processing, structure and properties (mechanical, chemical, electrical, electrochemical, magnetic and optical) of materials. Aspects of processing include the melting, casting, and fabrication with the thermodynamics, kinetics and modeling.