解锁同手性碳硼烷-融合硼菲蒽的合成

IF 19.6 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chem Pub Date : 2025-09-24 DOI:10.1016/j.chempr.2025.102779

Zheng Zhu, Yangjian Quan

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引用次数: 0

摘要

虽然不对称合成富集对映体碳硼烷衍生物已经公开，但同手性碳硼烷融合聚芳烃的合成仍然是难以捉摸的。在9月份的《细胞报告-物理科学》杂志上，Mu和他的同事们报道了含有碳硼烷块的各种硼菲蒽的模块化合成。机理研究表明，关键步骤是轴向手性转移和不寻常的1,2-硼迁移。

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Unlocking the synthesis of homochiral carborane-fused boraphenanthrenes

Although the asymmetric synthesis of enantioenriched carborane derivatives has been disclosed, the homochiral carborane-fused polyarene remains synthetically elusive. In the September issue of Cell Reports Physical Science, Mu and co-workers report the modular synthesis of various boraphenanthrenes containing carborane blocks. Mechanistic studies show that the key steps are the transfer of axial chirality and an unusual 1,2-boron migration.

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来源期刊

Chem Environmental Science-Environmental Chemistry

CiteScore

32.40

自引率

1.30%

发文量

281

期刊介绍： Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.