Yao Su, Zhiyong Liao, Xin Yang, Yongbo Fan, Dengwei Hu, Weijia Wang, Huiqing Fan
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Hydrogen Bond-Mediated Polar Structure Engineering of PVDF toward Superior Energy Storage
Dielectric capacitors have emerged as a pivotal class of energy storage devices in modern electronics. A major challenge is the low volumetric energy density hinders further development. To address this challenge, all-organic film has gained attention as a promising and scalable alternative. Here we developed an all-organic xylitol-PVDF film, which maximizes energy density by constructing a hydrogen bond network between PVDF and xylitol. The network enhances the crystallinity of PVDF, reduces the grain size of the α phase, β phase and γ phase, and increases the β phase content. The xylitol-PVDF composite film containing 5 wt% xylitol demonstrates a remarkable energy density of 23.64 J cm-3 and an impressive charge-discharged efficiency of 84.2%. A facile and scalable approach for fabricating high-performance PVDF-based dielectric film in this work, demonstrating exceptional energy storage performance.
期刊介绍:
The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.