面向高性能储能的氢键介导PVDF极性结构工程

IF 9.5 2区 材料科学 Q1 CHEMISTRY, PHYSICAL
Yao Su, Zhiyong Liao, Xin Yang, Yongbo Fan, Dengwei Hu, Weijia Wang, Huiqing Fan
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引用次数: 0

摘要

在现代电子学中,介电电容器已成为一种关键的能量存储装置。一个主要的挑战是低体积能量密度阻碍了进一步的发展。为了解决这一挑战,全有机薄膜作为一种有前途和可扩展的替代品受到了关注。在此,我们开发了一种全有机木糖醇-PVDF薄膜,通过在PVDF和木糖醇之间构建氢键网络,使能量密度最大化。该网络增强了PVDF的结晶度,减小了α相、β相和γ相的晶粒尺寸,增加了β相的含量。木糖醇- pvdf复合膜的能量密度为23.64 J cm-3,充放电效率为84.2%。在这项工作中,一种简便且可扩展的方法用于制造高性能pvdf基介电膜,展示了卓越的储能性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Hydrogen Bond-Mediated Polar Structure Engineering of PVDF toward Superior Energy Storage
Dielectric capacitors have emerged as a pivotal class of energy storage devices in modern electronics. A major challenge is the low volumetric energy density hinders further development. To address this challenge, all-organic film has gained attention as a promising and scalable alternative. Here we developed an all-organic xylitol-PVDF film, which maximizes energy density by constructing a hydrogen bond network between PVDF and xylitol. The network enhances the crystallinity of PVDF, reduces the grain size of the α phase, β phase and γ phase, and increases the β phase content. The xylitol-PVDF composite film containing 5 wt% xylitol demonstrates a remarkable energy density of 23.64 J cm-3 and an impressive charge-discharged efficiency of 84.2%. A facile and scalable approach for fabricating high-performance PVDF-based dielectric film in this work, demonstrating exceptional energy storage performance.
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来源期刊
Journal of Materials Chemistry A
Journal of Materials Chemistry A CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
19.50
自引率
5.00%
发文量
1892
审稿时长
1.5 months
期刊介绍: The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.
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