用于光伏和高能探测的单晶钙钛矿。

IF 39 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Bingyao Shao,Xin Song,Hongwei Zhu,Youcef A Bioud,Wentao Wu,Mutalifu Abulikemu,Hamad Saiari,Sarah Aqeel,Issam Gereige,Omar F Mohammed,Osman M Bakr
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引用次数: 0

摘要

金属卤化物钙钛矿由于具有高光吸收系数、可调带隙、长载流子扩散长度和高载流子迁移率等特点,在光电子领域得到了广泛的关注。它们与简单的低温加工方法的兼容性进一步确立了它们作为下一代半导体的前景。然而,多晶钙钛矿的本体和界面上存在大量缺陷,导致其稳定性差,阻碍了其商业化。相比之下,单晶(SC)钙钛矿含有更少的缺陷,因此具有固有的优越稳定性和光电性能,使其成为开发先进钙钛矿基器件的有前途的平台。本文全面分析了SC钙钛矿的优点,评价了各种晶体生长方法的优点和局限性,并重点介绍了它们在光伏和高能辐射检测中的应用。最后,我们讨论了阻碍SC钙钛矿实际实施的挑战,并提出了促进其大规模商业化的策略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Single-crystal perovskites for photovoltaic and high-energy detection applications.
Metal halide perovskites have garnered widespread attention for optoelectronic applications, owing to their high optical absorption coefficients, tunable bandgaps, long carrier diffusion lengths, and high carrier mobilities. Their compatibility with simple, low-temperature processing methods further establishes them as promising next-generation semiconductors. However, the numerous defects present in the bulk and at the interfaces of polycrystalline perovskites lead to poor stability, hindering their commercialization. In contrast, single-crystal (SC) perovskites contain far fewer defects and thus exhibit inherently superior stability and optoelectronic properties, making them a promising platform for developing advanced perovskite-based devices. This review provides a comprehensive analysis of the advantages of SC perovskites, evaluates the merits and limitations of various crystal growth methods, and highlights their use in photovoltaics and high-energy radiation detection. Finally, we discuss the challenges that hinder the practical implementation of SC perovskites and propose strategies to facilitate their large-scale commercialization.
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来源期刊
Chemical Society Reviews
Chemical Society Reviews 化学-化学综合
CiteScore
80.80
自引率
1.10%
发文量
345
审稿时长
6.0 months
期刊介绍: Chemical Society Reviews is published by: Royal Society of Chemistry. Focus: Review articles on topics of current interest in chemistry; Predecessors: Quarterly Reviews, Chemical Society (1947–1971); Current title: Since 1971; Impact factor: 60.615 (2021); Themed issues: Occasional themed issues on new and emerging areas of research in the chemical sciences
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