利用有机溶剂纳滤膜实现高沸点绿色溶剂回收。

IF 6.6 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
ChemSusChem Pub Date : 2025-09-23 DOI:10.1002/cssc.202501117
Marjolaine Thomas, Ana R Nabais, Maria J Burggraef, Ludmila Peeva, Jane Murray, Andrew G Livingston
{"title":"利用有机溶剂纳滤膜实现高沸点绿色溶剂回收。","authors":"Marjolaine Thomas, Ana R Nabais, Maria J Burggraef, Ludmila Peeva, Jane Murray, Andrew G Livingston","doi":"10.1002/cssc.202501117","DOIUrl":null,"url":null,"abstract":"<p><p>The extensive use of organic solvents in industrial processes contributes to environmental pollution, resource depletion, and human health hazards, incentivizing the development of more sustainable alternatives. In response, bio-based \"green\" solvents have emerged as environmentally benign substitutes, offering reduced toxicity and lower carbon footprints. However, their industrial implementation is challenged by high viscosity, energy-intensive recovery, and limited life-cycle sustainability when employed in single-use processes. Herein, organic solvent nanofiltration (OSN) as an energy-efficient and selective membrane-based technology for recycling green solvents is explored. OSN membranes enable solvent purification by selectively removing impurities while preserving solvent integrity, reducing waste generation and energy consumption. OSN performance in the recovery of widely used green solvents, including acetone, acetonitrile, ethyl acetate, Cyrene, dimethyl isosorbide (DMI), and γ-valerolactone (GVL), is evaluated. The potential of OSN for in-process solvent recycling is demonstrated, with a case study on the recycling of Cyrene in synthetic leather production, demonstrating the feasibility of OSN membranes in maintaining solvent purity and enabling a more sustainable manufacturing process.</p>","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e202501117"},"PeriodicalIF":6.6000,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enabling High-Boiling-Point Green Solvent Recycling Using Organic Solvent Nanofiltration Membranes.\",\"authors\":\"Marjolaine Thomas, Ana R Nabais, Maria J Burggraef, Ludmila Peeva, Jane Murray, Andrew G Livingston\",\"doi\":\"10.1002/cssc.202501117\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The extensive use of organic solvents in industrial processes contributes to environmental pollution, resource depletion, and human health hazards, incentivizing the development of more sustainable alternatives. In response, bio-based \\\"green\\\" solvents have emerged as environmentally benign substitutes, offering reduced toxicity and lower carbon footprints. However, their industrial implementation is challenged by high viscosity, energy-intensive recovery, and limited life-cycle sustainability when employed in single-use processes. Herein, organic solvent nanofiltration (OSN) as an energy-efficient and selective membrane-based technology for recycling green solvents is explored. OSN membranes enable solvent purification by selectively removing impurities while preserving solvent integrity, reducing waste generation and energy consumption. OSN performance in the recovery of widely used green solvents, including acetone, acetonitrile, ethyl acetate, Cyrene, dimethyl isosorbide (DMI), and γ-valerolactone (GVL), is evaluated. The potential of OSN for in-process solvent recycling is demonstrated, with a case study on the recycling of Cyrene in synthetic leather production, demonstrating the feasibility of OSN membranes in maintaining solvent purity and enabling a more sustainable manufacturing process.</p>\",\"PeriodicalId\":149,\"journal\":{\"name\":\"ChemSusChem\",\"volume\":\" \",\"pages\":\"e202501117\"},\"PeriodicalIF\":6.6000,\"publicationDate\":\"2025-09-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemSusChem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/cssc.202501117\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemSusChem","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/cssc.202501117","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

在工业过程中广泛使用有机溶剂会造成环境污染、资源枯竭和人类健康危害,从而鼓励开发更可持续的替代品。因此,生物基“绿色”溶剂作为环境友好的替代品出现了,它们的毒性更低,碳足迹更低。然而,它们的工业应用受到高粘度、能源密集型回收和有限的生命周期可持续性等问题的挑战。本文探讨了有机溶剂纳滤(OSN)作为一种高效、选择性的膜基绿色溶剂回收技术。OSN膜使溶剂净化选择性去除杂质,同时保持溶剂的完整性,减少废物的产生和能源消耗。评价了OSN在丙酮、乙腈、乙酸乙酯、Cyrene、二甲基异山梨酯(DMI)、γ-戊内酯(GVL)等常用绿色溶剂回收中的性能。通过对合成革生产中昔兰尼回收的案例研究,证明了OSN膜在保持溶剂纯度和实现更可持续的制造过程中的可行性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Enabling High-Boiling-Point Green Solvent Recycling Using Organic Solvent Nanofiltration Membranes.

The extensive use of organic solvents in industrial processes contributes to environmental pollution, resource depletion, and human health hazards, incentivizing the development of more sustainable alternatives. In response, bio-based "green" solvents have emerged as environmentally benign substitutes, offering reduced toxicity and lower carbon footprints. However, their industrial implementation is challenged by high viscosity, energy-intensive recovery, and limited life-cycle sustainability when employed in single-use processes. Herein, organic solvent nanofiltration (OSN) as an energy-efficient and selective membrane-based technology for recycling green solvents is explored. OSN membranes enable solvent purification by selectively removing impurities while preserving solvent integrity, reducing waste generation and energy consumption. OSN performance in the recovery of widely used green solvents, including acetone, acetonitrile, ethyl acetate, Cyrene, dimethyl isosorbide (DMI), and γ-valerolactone (GVL), is evaluated. The potential of OSN for in-process solvent recycling is demonstrated, with a case study on the recycling of Cyrene in synthetic leather production, demonstrating the feasibility of OSN membranes in maintaining solvent purity and enabling a more sustainable manufacturing process.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
ChemSusChem
ChemSusChem 化学-化学综合
CiteScore
15.80
自引率
4.80%
发文量
555
审稿时长
1.8 months
期刊介绍: ChemSusChem Impact Factor (2016): 7.226 Scope: Interdisciplinary journal Focuses on research at the interface of chemistry and sustainability Features the best research on sustainability and energy Areas Covered: Chemistry Materials Science Chemical Engineering Biotechnology
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信