微波辐照Fe2O3活性炭的电化学性能研究

IF 1.8 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER
R. Manigandan, P. Thirupura Sundari, S. Aravindhan, S. Srinivasan, A. P. Lingaswamy
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引用次数: 0

摘要

本研究采用简单的共沉淀法合成和修饰Fe2O3纳米颗粒,然后通过微波辐照和活性炭掺入来增强其结构、光学和电化学性能。x射线衍射(XRD)分析证实了赤铁矿(α-Fe2O3)呈菱形相,微波辐照后晶格应变增强,活性位点密度提高。紫外可见光谱显示,带隙从2.5 eV(纯Fe2O3)显著降低到1.6 eV(微波辐照的Fe2O3与活性炭),表明优越的光吸收。电化学表征表明,微波辐照的Fe2O3与活性炭的氧化还原活性和比电容有所提高,由于电导率和孔隙率的提高,Fe2O3达到了最高的性能。这些结果突出了微波辐照和活性炭的协同效应,使改性Fe2O3在催化、储能和光电子方面的应用前景广阔。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Study of Microwave-Irradiated Fe2O3 with Activated Charcoal for Superior Electrochemical Performance

Study of Microwave-Irradiated Fe2O3 with Activated Charcoal for Superior Electrochemical Performance

This study presents the synthesis and modification of Fe2O3 nanoparticles using a simple co-precipitation method, followed by microwave irradiation and incorporation with activated charcoal to enhance their structural, optical, and electrochemical properties. X-ray diffraction (XRD) analysis confirmed the rhombohedral phase of hematite (α-Fe2O3) and revealed enhanced lattice strain upon microwave irradiation improving active site density. UV-Vis spectroscopy showed a significant bandgap reduction from 2.5 eV (pure Fe2O3) to 1.6 eV (microwave-irradiated Fe2O3 with activated charcoal) indicating superior light absorption. Electrochemical characterization demonstrated improved redox activity and specific capacitance, with microwave-irradiated Fe2O3 with activated charcoal achieving the highest performance due to enhanced conductivity and porosity. These results highlight the synergistic effects of microwave irradiation and activated charcoal making the modified Fe2O3 a promising candidate for applications in catalysis, energy storage, and optoelectronics.

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来源期刊
Physics of the Solid State
Physics of the Solid State 物理-物理:凝聚态物理
CiteScore
1.70
自引率
0.00%
发文量
60
审稿时长
2-4 weeks
期刊介绍: Presents the latest results from Russia’s leading researchers in condensed matter physics at the Russian Academy of Sciences and other prestigious institutions. Covers all areas of solid state physics including solid state optics, solid state acoustics, electronic and vibrational spectra, phase transitions, ferroelectricity, magnetism, and superconductivity. Also presents review papers on the most important problems in solid state physics.
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