{"title":"钙掺杂对Sr1-xCaxTiO3陶瓷物理、微观结构和电学特性的影响","authors":"Jakkula Shankar, Paramesh Donta, Raju Panthagani","doi":"10.1134/S1063783425600220","DOIUrl":null,"url":null,"abstract":"<p>The strontium calcium titanate (Sr<sub>1–<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub>) ceramics have been synthesized using the solid-state reaction method. Sr<sub>1–<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub> ceramics are sintered at 1300°C for 3 h. The X-ray diffraction confirmed perovskite tetragonal strontium calcium titanate ceramics. It is found that with the increase of calcium content in Sr<sub>1–<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub> the unit cell volume and density decrease. The microstructure of strontium calcium titanate is examined using field emission scanning electron microscopy it is found that with the addition of calcium, the average grain size has increased for all compositions of Sr<sub>1–<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub> ceramics. Porosity is decreased with the addition of calcium in Sr<sub>1–<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub> ceramics. The variation of relative permittivity (ɛ<sub>r</sub>) and loss tangent (tanδ) with temperature in Sr<sub>1–<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub> ceramics was observed to remain constant up to 200°C and beyond this temperature ɛ<sub>r</sub> and tan δ enhanced with a rise in Calcium content.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"67 7","pages":"533 - 539"},"PeriodicalIF":1.8000,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of Calcium Doping on the Physical, Microstructural, and Electrical Characteristics of Sr1–xCaxTiO3 Ceramics\",\"authors\":\"Jakkula Shankar, Paramesh Donta, Raju Panthagani\",\"doi\":\"10.1134/S1063783425600220\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The strontium calcium titanate (Sr<sub>1–<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub>) ceramics have been synthesized using the solid-state reaction method. Sr<sub>1–<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub> ceramics are sintered at 1300°C for 3 h. The X-ray diffraction confirmed perovskite tetragonal strontium calcium titanate ceramics. It is found that with the increase of calcium content in Sr<sub>1–<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub> the unit cell volume and density decrease. The microstructure of strontium calcium titanate is examined using field emission scanning electron microscopy it is found that with the addition of calcium, the average grain size has increased for all compositions of Sr<sub>1–<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub> ceramics. Porosity is decreased with the addition of calcium in Sr<sub>1–<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub> ceramics. The variation of relative permittivity (ɛ<sub>r</sub>) and loss tangent (tanδ) with temperature in Sr<sub>1–<i>x</i></sub>Ca<sub><i>x</i></sub>TiO<sub>3</sub> ceramics was observed to remain constant up to 200°C and beyond this temperature ɛ<sub>r</sub> and tan δ enhanced with a rise in Calcium content.</p>\",\"PeriodicalId\":731,\"journal\":{\"name\":\"Physics of the Solid State\",\"volume\":\"67 7\",\"pages\":\"533 - 539\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2025-07-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physics of the Solid State\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1063783425600220\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physics of the Solid State","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1134/S1063783425600220","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
Influence of Calcium Doping on the Physical, Microstructural, and Electrical Characteristics of Sr1–xCaxTiO3 Ceramics
The strontium calcium titanate (Sr1–xCaxTiO3) ceramics have been synthesized using the solid-state reaction method. Sr1–xCaxTiO3 ceramics are sintered at 1300°C for 3 h. The X-ray diffraction confirmed perovskite tetragonal strontium calcium titanate ceramics. It is found that with the increase of calcium content in Sr1–xCaxTiO3 the unit cell volume and density decrease. The microstructure of strontium calcium titanate is examined using field emission scanning electron microscopy it is found that with the addition of calcium, the average grain size has increased for all compositions of Sr1–xCaxTiO3 ceramics. Porosity is decreased with the addition of calcium in Sr1–xCaxTiO3 ceramics. The variation of relative permittivity (ɛr) and loss tangent (tanδ) with temperature in Sr1–xCaxTiO3 ceramics was observed to remain constant up to 200°C and beyond this temperature ɛr and tan δ enhanced with a rise in Calcium content.
期刊介绍：
Presents the latest results from Russia’s leading researchers in condensed matter physics at the Russian Academy of Sciences and other prestigious institutions. Covers all areas of solid state physics including solid state optics, solid state acoustics, electronic and vibrational spectra, phase transitions, ferroelectricity, magnetism, and superconductivity. Also presents review papers on the most important problems in solid state physics.
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