高性能多参数发光温度计:掺Dy3+铝硼酸钠玻璃

IF 3.6 3区 物理与天体物理 Q2 OPTICS
Aleksandar Ćirić , Aytaç Gürhan Gökçe , Melis Gökçe , Sanja Kuzman , Zoran Ristić , Bojana Milićević , Deniz Koçyiğit , Miroslav D. Dramićanin
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引用次数: 0

摘要

本文介绍了使用掺Dy3+铝硼酸钠玻璃进行高性能多参数发光测温的综合研究。采用熔淬法合成了该玻璃,并对其进行了结构和光学表征。研究了温度依赖性发光特性,重点研究了热耦合Dy3+跃迁的发光强度比(LIR)、发射带宽和线移。应用Judd-Ofelt模型解释了测温行为,与实验结果非常吻合。虽然发光寿命保持温度不变,使材料不适合基于寿命的测温,但稳态光谱特征提供了高灵敏度和精度。采用多参数方法,包括多元线性回归(MLR)和传感器融合(SF),将不同的读数组合在一起,从而提高温度分辨率和鲁棒性。特别是,传感器融合方法优于基于单个和mlr的方法,在所有温度下都能实现亚开尔文温度分辨率。这些发现表明,在苛刻的环境中,Dy3+掺杂铝硼酸钠玻璃是可靠的、高精度的发光测温的有希望的候选材料,并且多参数方法MLR和SF优于单个参数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
High-performance multiparametric luminescent thermometer: Dy3+-doped sodium alumino-borate glass
This work presents a comprehensive study of high-performance multiparametric luminescent thermometry using Dy3+-doped sodium alumino-borate glass. The glass was synthesized via the melt-quenching method and characterized structurally and optically. Temperature-dependent luminescence properties were investigated, focusing on the luminescence intensity ratio (LIR) of thermally coupled Dy3+ transitions, as well as emission bandwidth and line shift. The Judd-Ofelt model was applied to interpret the thermometric behaviour, showing excellent agreement with experimental results. While the luminescence lifetime remained temperature-invariant, making the material unsuitable for lifetime-based thermometry, steady-state spectral features provided high sensitivity and precision. Multiparametric approaches, including multiple linear regression (MLR) and sensor fusion (SF), were employed to combine different readouts, resulting in enhanced temperature resolution and robustness. The sensor fusion method, in particular, outperformed individual and MLR-based approaches, achieving sub-kelvin temperature resolution at all temperatures. These findings demonstrate that Dy3+-doped sodium alumino-borate glass is a promising candidate for reliable, high-precision luminescent thermometry in demanding environments and the power of multiparametric methods MLR and SF over the individual parameters.
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来源期刊
Journal of Luminescence
Journal of Luminescence 物理-光学
CiteScore
6.70
自引率
13.90%
发文量
850
审稿时长
3.8 months
期刊介绍: The purpose of the Journal of Luminescence is to provide a means of communication between scientists in different disciplines who share a common interest in the electronic excited states of molecular, ionic and covalent systems, whether crystalline, amorphous, or liquid. We invite original papers and reviews on such subjects as: exciton and polariton dynamics, dynamics of localized excited states, energy and charge transport in ordered and disordered systems, radiative and non-radiative recombination, relaxation processes, vibronic interactions in electronic excited states, photochemistry in condensed systems, excited state resonance, double resonance, spin dynamics, selective excitation spectroscopy, hole burning, coherent processes in excited states, (e.g. coherent optical transients, photon echoes, transient gratings), multiphoton processes, optical bistability, photochromism, and new techniques for the study of excited states. This list is not intended to be exhaustive. Papers in the traditional areas of optical spectroscopy (absorption, MCD, luminescence, Raman scattering) are welcome. Papers on applications (phosphors, scintillators, electro- and cathodo-luminescence, radiography, bioimaging, solar energy, energy conversion, etc.) are also welcome if they present results of scientific, rather than only technological interest. However, papers containing purely theoretical results, not related to phenomena in the excited states, as well as papers using luminescence spectroscopy to perform routine analytical chemistry or biochemistry procedures, are outside the scope of the journal. Some exceptions will be possible at the discretion of the editors.
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