Chao Li , Lei Pang , Zhaoran Wang , Jiqing Liu , Siheng Sun , Zhenbao Li , Chunmiao Yuan
{"title":"填料结构对AlMg合金粉末热致自燃的影响","authors":"Chao Li , Lei Pang , Zhaoran Wang , Jiqing Liu , Siheng Sun , Zhenbao Li , Chunmiao Yuan","doi":"10.1016/j.powtec.2025.121669","DOIUrl":null,"url":null,"abstract":"<div><div>Al<img>Mg alloy powder's wide use in 3D printing and energetic materials poses major thermal self-ignition risks to energy development and safety. In this study, a custom-designed experimental system was developed to systematically investigate how various dust packing structures influence the self-ignition characteristics of Al<img>Mg alloy powder under thermal stimulation. Through spatiotemporal analysis of temperature evolution, flame propagation behavior, and visualized thermal diffusion pathways, we reveal the dominant role of packing configurations in governing heat transfer and ignition risk. The results demonstrate that stacked Al<img>Mg alloy powders exhibit a relatively low minimum self-ignition temperature, occurring at only about 310–320 °C. For 60 μm powders, the mass increase reached 187 % at 1298 °C. Moreover, finer powders exhibited multi-stage exothermic behaviors, reflecting more complex oxidation pathways. Among the tested configurations, the uniformly spread structure of 60 μm powders showed the highest heating rate, with an internal temperature rise up to 134.4 °C/min, owing to its short thermal conduction path and efficient heat transfer.This structure consistently exhibited higher (d<em>T</em>/dt)<sub>max</sub>, the fastest temperature rise, and the most severe ignition hazard, with a distinct concentric flame propagation pattern. In contrast, natural packing presents an “outside-to-top, layer-by-layer combustion” behavior, while side-stacked configurations display “unidirectional lateral flame spread.” A machine learning approach was employed for clustering of key thermal parameters, enabling classification of ignition risks and predictive assessment of hazardous conditions. This work elucidates the mechanisms by which packing structures modulate thermal ignition behavior and offers data-driven insights for the safe design and management of high-energy powder materials.</div></div>","PeriodicalId":407,"journal":{"name":"Powder Technology","volume":"468 ","pages":"Article 121669"},"PeriodicalIF":4.6000,"publicationDate":"2025-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of packing structure on the thermal-induced self-ignition of AlMg alloy powder\",\"authors\":\"Chao Li , Lei Pang , Zhaoran Wang , Jiqing Liu , Siheng Sun , Zhenbao Li , Chunmiao Yuan\",\"doi\":\"10.1016/j.powtec.2025.121669\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Al<img>Mg alloy powder's wide use in 3D printing and energetic materials poses major thermal self-ignition risks to energy development and safety. In this study, a custom-designed experimental system was developed to systematically investigate how various dust packing structures influence the self-ignition characteristics of Al<img>Mg alloy powder under thermal stimulation. Through spatiotemporal analysis of temperature evolution, flame propagation behavior, and visualized thermal diffusion pathways, we reveal the dominant role of packing configurations in governing heat transfer and ignition risk. The results demonstrate that stacked Al<img>Mg alloy powders exhibit a relatively low minimum self-ignition temperature, occurring at only about 310–320 °C. For 60 μm powders, the mass increase reached 187 % at 1298 °C. Moreover, finer powders exhibited multi-stage exothermic behaviors, reflecting more complex oxidation pathways. Among the tested configurations, the uniformly spread structure of 60 μm powders showed the highest heating rate, with an internal temperature rise up to 134.4 °C/min, owing to its short thermal conduction path and efficient heat transfer.This structure consistently exhibited higher (d<em>T</em>/dt)<sub>max</sub>, the fastest temperature rise, and the most severe ignition hazard, with a distinct concentric flame propagation pattern. In contrast, natural packing presents an “outside-to-top, layer-by-layer combustion” behavior, while side-stacked configurations display “unidirectional lateral flame spread.” A machine learning approach was employed for clustering of key thermal parameters, enabling classification of ignition risks and predictive assessment of hazardous conditions. This work elucidates the mechanisms by which packing structures modulate thermal ignition behavior and offers data-driven insights for the safe design and management of high-energy powder materials.</div></div>\",\"PeriodicalId\":407,\"journal\":{\"name\":\"Powder Technology\",\"volume\":\"468 \",\"pages\":\"Article 121669\"},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2025-09-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Powder Technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0032591025010642\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Powder Technology","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0032591025010642","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Influence of packing structure on the thermal-induced self-ignition of AlMg alloy powder
AlMg alloy powder's wide use in 3D printing and energetic materials poses major thermal self-ignition risks to energy development and safety. In this study, a custom-designed experimental system was developed to systematically investigate how various dust packing structures influence the self-ignition characteristics of AlMg alloy powder under thermal stimulation. Through spatiotemporal analysis of temperature evolution, flame propagation behavior, and visualized thermal diffusion pathways, we reveal the dominant role of packing configurations in governing heat transfer and ignition risk. The results demonstrate that stacked AlMg alloy powders exhibit a relatively low minimum self-ignition temperature, occurring at only about 310–320 °C. For 60 μm powders, the mass increase reached 187 % at 1298 °C. Moreover, finer powders exhibited multi-stage exothermic behaviors, reflecting more complex oxidation pathways. Among the tested configurations, the uniformly spread structure of 60 μm powders showed the highest heating rate, with an internal temperature rise up to 134.4 °C/min, owing to its short thermal conduction path and efficient heat transfer.This structure consistently exhibited higher (dT/dt)max, the fastest temperature rise, and the most severe ignition hazard, with a distinct concentric flame propagation pattern. In contrast, natural packing presents an “outside-to-top, layer-by-layer combustion” behavior, while side-stacked configurations display “unidirectional lateral flame spread.” A machine learning approach was employed for clustering of key thermal parameters, enabling classification of ignition risks and predictive assessment of hazardous conditions. This work elucidates the mechanisms by which packing structures modulate thermal ignition behavior and offers data-driven insights for the safe design and management of high-energy powder materials.
期刊介绍:
Powder Technology is an International Journal on the Science and Technology of Wet and Dry Particulate Systems. Powder Technology publishes papers on all aspects of the formation of particles and their characterisation and on the study of systems containing particulate solids. No limitation is imposed on the size of the particles, which may range from nanometre scale, as in pigments or aerosols, to that of mined or quarried materials. The following list of topics is not intended to be comprehensive, but rather to indicate typical subjects which fall within the scope of the journal's interests:
Formation and synthesis of particles by precipitation and other methods.
Modification of particles by agglomeration, coating, comminution and attrition.
Characterisation of the size, shape, surface area, pore structure and strength of particles and agglomerates (including the origins and effects of inter particle forces).
Packing, failure, flow and permeability of assemblies of particles.
Particle-particle interactions and suspension rheology.
Handling and processing operations such as slurry flow, fluidization, pneumatic conveying.
Interactions between particles and their environment, including delivery of particulate products to the body.
Applications of particle technology in production of pharmaceuticals, chemicals, foods, pigments, structural, and functional materials and in environmental and energy related matters.
For materials-oriented contributions we are looking for articles revealing the effect of particle/powder characteristics (size, morphology and composition, in that order) on material performance or functionality and, ideally, comparison to any industrial standard.