金属离子改性ZSM-5沸石抑制甲烷爆炸的实验研究

IF 4.2 3区 工程技术 Q2 ENGINEERING, CHEMICAL
Zhengqi Wu , Siqi Wang , Yongmei Hao , Fan Wu , Yuhao Liang , Ning Xu
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引用次数: 0

摘要

为了提高ZSM-5沸石对甲烷爆炸的抑制效果,合成了多种含金属离子的ZSM-5沸石复合粉,并进行了甲烷爆炸实验,考察了不同金属离子改性ZSM-5沸石对甲烷爆炸的抑制效果。通过扫描电镜、XRD分析等技术手段对改性后的沸石粉体进行了表征和分析,并与未改性沸石粉体的抑爆效果进行了比较。结果表明,经金属离子改性的沸石粉具有较好的抑爆效果,其中加入K+/ZSM-5沸石抑爆粉后的甲烷爆炸压力最低,最大爆炸压力较未喷粉条件降低了78.88%。本研究考察了抑制粉的爆炸抑制效果,包括吸附、屏障形成和爆炸过程中产生的自由基的消耗。抑爆粉中的金属离子与甲烷爆炸过程中产生的自由基相互作用,阻断链式反应,抑制爆炸。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Experimental study on the explosion suppression of methane by metal ion modified ZSM-5 zeolite
To enhance the inhibitory efficacy of ZSM-5 zeolite against methane explosions, various composite powders of ZSM-5 zeolite incorporating metal ions were synthesized, and methane explosion experiments were conducted to investigate the impact of different metal ion-modified ZSM-5 zeolites on methane explosion suppression. The modified zeolite powders were characterized and analyzed by technical means such as scanning electron microscopy and XRD analysis, and finally compared with the explosion suppression effect of the unmodified zeolite powder. The results show that the zeolite powder modified by metal ions has a better explosion suppression effect, and among them, the methane explosion pressure with the addition of K+/ZSM-5 zeolite explosion suppression powder is the lowest, and the maximum explosion pressure is reduced by 78.88 % compared with the non-powder spraying condition. This study examines the explosion suppression efficacy of the suppression powder, which encompasses adsorption, barrier formation, and the consumption of free radicals produced during the explosion process. The metal ions in the explosion suppression powder interact with the free radicals produced during the methane explosion, thereby blocking the chain reaction and suppressing the explosion.
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来源期刊
CiteScore
7.20
自引率
14.30%
发文量
226
审稿时长
52 days
期刊介绍: The broad scope of the journal is process safety. Process safety is defined as the prevention and mitigation of process-related injuries and damage arising from process incidents involving fire, explosion and toxic release. Such undesired events occur in the process industries during the use, storage, manufacture, handling, and transportation of highly hazardous chemicals.
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